皮革与化工
皮革與化工
피혁여화공
LEATHER AND CHEMICALS
2015年
1期
5-7,15
,共4页
俞凌云%吴孟茹%金晶%温演庆%车颖欣%董伟
俞凌雲%吳孟茹%金晶%溫縯慶%車穎訢%董偉
유릉운%오맹여%금정%온연경%차영흔%동위
超高效液相色谱%α- 吡咯烷酮%N- 甲基吡咯烷酮(NMP)%N- 乙基吡咯烷酮%轻工产品
超高效液相色譜%α- 吡咯烷酮%N- 甲基吡咯烷酮(NMP)%N- 乙基吡咯烷酮%輕工產品
초고효액상색보%α- 필각완동%N- 갑기필각완동(NMP)%N- 을기필각완동%경공산품
UPLC%2-Pyrrolidone%N-methyl pyrrolidone%N-ethyl pyrrolidone%light industrial products
2-吡咯烷酮(PYR)、N-甲基吡咯烷酮(NMP)、N-乙基吡咯烷酮(NEP)是一类优良的有机溶剂,因其潜在的生殖毒性而被关注。本文利用超高效液相色谱-二极管阵列检测器建立检测皮革中PYR、NMP、NEP的简单方法,样品提取方法为40℃超声水浴提取,提取溶液为0.1%十二烷基磺酸钠水溶液。在优化的色谱条件下,三种吡咯酮的检出限在20μg/L~40μg/L,其回收率高于91.6%。这个方法被成功应用于测定轻工产品中的2-吡咯烷酮、N-甲基吡咯烷酮和N-乙基吡咯烷酮,比传统的气相色谱法准确度高,且提取步骤简单。
2-吡咯烷酮(PYR)、N-甲基吡咯烷酮(NMP)、N-乙基吡咯烷酮(NEP)是一類優良的有機溶劑,因其潛在的生殖毒性而被關註。本文利用超高效液相色譜-二極管陣列檢測器建立檢測皮革中PYR、NMP、NEP的簡單方法,樣品提取方法為40℃超聲水浴提取,提取溶液為0.1%十二烷基磺痠鈉水溶液。在優化的色譜條件下,三種吡咯酮的檢齣限在20μg/L~40μg/L,其迴收率高于91.6%。這箇方法被成功應用于測定輕工產品中的2-吡咯烷酮、N-甲基吡咯烷酮和N-乙基吡咯烷酮,比傳統的氣相色譜法準確度高,且提取步驟簡單。
2-필각완동(PYR)、N-갑기필각완동(NMP)、N-을기필각완동(NEP)시일류우량적유궤용제,인기잠재적생식독성이피관주。본문이용초고효액상색보-이겁관진렬검측기건립검측피혁중PYR、NMP、NEP적간단방법,양품제취방법위40℃초성수욕제취,제취용액위0.1%십이완기광산납수용액。재우화적색보조건하,삼충필각동적검출한재20μg/L~40μg/L,기회수솔고우91.6%。저개방법피성공응용우측정경공산품중적2-필각완동、N-갑기필각완동화N-을기필각완동,비전통적기상색보법준학도고,차제취보취간단。
2-pyrrolidone (PYR), N-methyl pyrrolidone (NMP) and N-ethyl pyrrolidone (NEP) are a kind of excellent organic solvent, which have been focused on because of their potential reproductive toxicity. A simple method followed by ultra performance liquid chromatography (UPLC) with Photo-Diode Array detector (PDA) has been developed for the determination of 2-Pyrrolidone, N-methyl pyrrolidone and N-ethyl pyrrolidone in leather samples. 0.1% sodium dodecyl sulfonate aqueous solution was used for the ultrasonic extraction at 40℃. Under optimal conditions, the quantification limits for the desired compounds ranging from 20 to 40μg/L were obtained. The recoveries were higher than 91.6% . The proposed method was successfully applied to the determination of the target compounds in light industrial products with a higher sensitivity and simpler extraction than traditional gas chromatography methods.