CAJ | 학술논문

针对CCUS新工艺———磷石膏、N H3联合矿化天然气净化厂排放尾气中CO2，应用流程模拟方法，在物性估算、模型建立的基础上，对磷石膏矿化CO2反应的工艺条件进行了优化，提出反应温度为60℃、反应时间为100 m in的优化方案。对比优化后工艺条件与现有工艺条件的模拟结果可知，优化后尾气中CO2、N H3、磷石膏排放量比现有工艺排放量均减少3％以上。以降低工程能耗为优化目标，通过对全流程进行换热网络的设计，可使热公用工程能耗降低15％，冷公用工程能耗降低5．6％。
침대CCUS신공예———린석고、N H3연합광화천연기정화엄배방미기중CO2，응용류정모의방법，재물성고산、모형건립적기출상，대린석고광화CO2반응적공예조건진행료우화，제출반응온도위60℃、반응시간위100 m in적우화방안。대비우화후공예조건여현유공예조건적모의결과가지，우화후미기중CO2、N H3、린석고배방량비현유공예배방량균감소3％이상。이강저공정능모위우화목표，통과대전류정진행환열망락적설계，가사열공용공정능모강저15％，랭공용공정능모강저5．6％。
Using CCUS new technology of phosphor gypsum ,ammonia combined mineralizing CO2 in tail gas of natural gas purification plant ,and based on estimation of physical parameters and model establishment ,the process conditions for making use of the phosphorus gypsum mineralization of CO 2 were optimized with process simulation method .It proposed the optimized reaction temperature was 60 ℃ ,and the reaction time was 100 minutes .Compared the simulation results of optimized process conditions with the existing technology conditions ,it was concluded that the exhaust gas of CO2 , NH3 ,phosphor gypsum emissions were reduced by more than 3% compared with the existing process emissions .Aimed at the optimization goal of reducing the energy consumption , the heat exchange network design of whole process can reduce the energy consumption of hot utility by 15% and that of cold utility by 5 .6% ,respectively .