合成材料老化与应用
閤成材料老化與應用
합성재료노화여응용
SYNTHETIC MATERIALS AGING AND APPLICATION
2015年
1期
19-22
,共4页
胡玉娟%麦伟宗%苏仕琼%黄李胜%李景
鬍玉娟%麥偉宗%囌仕瓊%黃李勝%李景
호옥연%맥위종%소사경%황리성%리경
增强阻燃聚碳酸酯%国网智能电表外壳材料%卤系与有机硅复配阻燃剂
增彊阻燃聚碳痠酯%國網智能電錶外殼材料%滷繫與有機硅複配阻燃劑
증강조연취탄산지%국망지능전표외각재료%서계여유궤규복배조연제
flame-retardant glass fiber reinforced PC%state grids smart meter shell materials%compounded flame retardants of brominated tribromophenoxy with silicone
控制玻璃纤维除去含量为10%,将PC树脂与增韧剂、阻燃剂、抗氧剂等助剂经预混,经过双螺杆挤出机制备了增强阻燃聚碳酸酯胶粒,用于注塑国网电表外壳。文章研究了玻璃纤维与相容剂的含量对材料力学性能的影响,并探索了溴代三嗪阻燃剂与有机硅阻燃剂对材料阻燃性能与力学的影响。结果表明玻璃纤维含量为10%时PC的冲击性能下降较大,选用马来酸酐接枝聚烯烃相容剂能改善这一状况;阻燃材料达到V0级阻燃时,溴代三嗪添加量为5%,此添加量会降低了材料力学性能。有机硅阻燃剂添加1.5%达到V0级阻燃,此添加量提高了材料力学性能。将二者复配使用,不仅具有阻燃协效作用,而且具有更低的成本。
控製玻璃纖維除去含量為10%,將PC樹脂與增韌劑、阻燃劑、抗氧劑等助劑經預混,經過雙螺桿擠齣機製備瞭增彊阻燃聚碳痠酯膠粒,用于註塑國網電錶外殼。文章研究瞭玻璃纖維與相容劑的含量對材料力學性能的影響,併探索瞭溴代三嗪阻燃劑與有機硅阻燃劑對材料阻燃性能與力學的影響。結果錶明玻璃纖維含量為10%時PC的遲擊性能下降較大,選用馬來痠酐接枝聚烯烴相容劑能改善這一狀況;阻燃材料達到V0級阻燃時,溴代三嗪添加量為5%,此添加量會降低瞭材料力學性能。有機硅阻燃劑添加1.5%達到V0級阻燃,此添加量提高瞭材料力學性能。將二者複配使用,不僅具有阻燃協效作用,而且具有更低的成本。
공제파리섬유제거함량위10%,장PC수지여증인제、조연제、항양제등조제경예혼,경과쌍라간제출궤제비료증강조연취탄산지효립,용우주소국망전표외각。문장연구료파리섬유여상용제적함량대재료역학성능적영향,병탐색료추대삼진조연제여유궤규조연제대재료조연성능여역학적영향。결과표명파리섬유함량위10%시PC적충격성능하강교대,선용마래산항접지취희경상용제능개선저일상황;조연재료체도V0급조연시,추대삼진첨가량위5%,차첨가량회강저료재료역학성능。유궤규조연제첨가1.5%체도V0급조연,차첨가량제고료재료역학성능。장이자복배사용,불부구유조연협효작용,이차구유경저적성본。
Flame retardant and glass fiber reinforced polycarbonate( PC) modified with 10% glass fiber,compati-bilizer,flame retardant,antioxidant and other additives was prepared via a parallel twin-screw extruder for injecting state grids smart meter shell. In this paper,the effect of glass fiber and compatibilizer dosage to mechanical proper-ties of PC was studied,the effect of brominated tribromophenoxy and silicone to flame retardancy and mechanical properties was also researched. The results indicated that material’s impact strength was decreased with 10 wt%glass fiber,and 5 wt% maleic anhydride grafted polyolefin compatibilizer could improve the situation. With the ad-dition of 5 wt% brominated tribromophenoxy or 1. 5 wt% silicone,UL-94 -V0 could be achieved. The former flame retardant could reduce mechanical properties of material and the latter one was just opposite. Compounded brominated tribromophenoxy with silicone,a material which has good properties and lower costs was achieved.