合成材料老化与应用
閤成材料老化與應用
합성재료노화여응용
SYNTHETIC MATERIALS AGING AND APPLICATION
2015年
1期
9-11,15
,共4页
刘钰馨%莫羡忠%庞锦英%杨芳%李建鸣
劉鈺馨%莫羨忠%龐錦英%楊芳%李建鳴
류옥형%막이충%방금영%양방%리건명
木薯淀粉%聚乙烯醇%二氧化硅%稳定性能
木藷澱粉%聚乙烯醇%二氧化硅%穩定性能
목서정분%취을희순%이양화규%은정성능
cassava starch%PVA%SiO2%stability
通过添加聚乙烯醇( PVA)、二氧化硅( SiO2)到木薯淀粉中,采用熔融密炼法制备热塑性木薯淀粉( TPS)/PVA/SiO2共混材料,研究共混材料的吸水性、生物降解与熔融行为。研究结果表明:随着SiO2用量的增加, TPS/PVA/SiO2共混体系的吸水率增加, TPS/PVA (1799)/SiO2共混材料的吸水率高于 TPS/PVA (1788)/SiO2共混物。表面改性后SiO2的TPS/PVA/SiO2共混物的吸水率低于未改性SiO2。随着SiO2用量的增加,TPS/PVA/SiO2共混物的生物降解降低,共混物的熔融峰增高,而熔融焓降低。
通過添加聚乙烯醇( PVA)、二氧化硅( SiO2)到木藷澱粉中,採用鎔融密煉法製備熱塑性木藷澱粉( TPS)/PVA/SiO2共混材料,研究共混材料的吸水性、生物降解與鎔融行為。研究結果錶明:隨著SiO2用量的增加, TPS/PVA/SiO2共混體繫的吸水率增加, TPS/PVA (1799)/SiO2共混材料的吸水率高于 TPS/PVA (1788)/SiO2共混物。錶麵改性後SiO2的TPS/PVA/SiO2共混物的吸水率低于未改性SiO2。隨著SiO2用量的增加,TPS/PVA/SiO2共混物的生物降解降低,共混物的鎔融峰增高,而鎔融焓降低。
통과첨가취을희순( PVA)、이양화규( SiO2)도목서정분중,채용용융밀련법제비열소성목서정분( TPS)/PVA/SiO2공혼재료,연구공혼재료적흡수성、생물강해여용융행위。연구결과표명:수착SiO2용량적증가, TPS/PVA/SiO2공혼체계적흡수솔증가, TPS/PVA (1799)/SiO2공혼재료적흡수솔고우 TPS/PVA (1788)/SiO2공혼물。표면개성후SiO2적TPS/PVA/SiO2공혼물적흡수솔저우미개성SiO2。수착SiO2용량적증가,TPS/PVA/SiO2공혼물적생물강해강저,공혼물적용융봉증고,이용융함강저。
The thermoplastic tapioca starch( TPS)/PVA/SiO2 blends were prepared through melt mixing meth-od,by adding polyvinyl alcohol(PVA),silica(SiO2)into cassava starch,and the water absorption,biodegradation, and melting behavior of the blends were investigated. The research results indicated that with the increase of SiO2 content,the water absorption of TPS/PVA/SiO2 blends increased,and the water absorption of TPS/PVA(1799)/SiO2 blends was higher than that of TPS/PVA(1788)/SiO2 blends. The water absorption of TPS/PVA/SiO2 blends with SiO2 surface treated was lower than that of the untreated SiO2. With the increase of the SiO2 content,the bio-degradation of TPS/PVA/SiO2 blends decreased,the melting peak of the blends increased,however the melting en-thalpy decreased.