CAJ | 학술논문

采用实验室气流床反应器，在H2O、O2及其混合气氛，900℃条件下进行了胜利褐煤气化实验，研究了气化半焦的孔隙结构特征。结果表明，在所有气氛下，半焦的吸附等温线均属于第II类型，吸附回线为H3型，褐煤气化半焦具有连续的较完整的孔体系，孔隙结构类似。反应气氛影响气化半焦的孔径分布，半焦中的大孔在3种气氛下均较少，中孔从多到少的顺序是：H2O>O2>H2O+1%O2，微孔与之相反。在水蒸气气氛下，随水蒸气浓度增加，半焦的比表面积先增大后趋于稳定。添加1%O2后，比表面积提升30多倍。低浓度O2气氛下，随O2浓度的增加，比表面积呈线性增长。褐煤转化率与微孔容积和总孔容积的比值以及比表面积的关系式为X=0.196(Vm/V)+45.651，X=0.037S+48.066。
채용실험실기류상반응기，재H2O、O2급기혼합기분，900℃조건하진행료성리갈매기화실험，연구료기화반초적공극결구특정。결과표명，재소유기분하，반초적흡부등온선균속우제II류형，흡부회선위H3형，갈매기화반초구유련속적교완정적공체계，공극결구유사。반응기분영향기화반초적공경분포，반초중적대공재3충기분하균교소，중공종다도소적순서시：H2O>O2>H2O+1%O2，미공여지상반。재수증기기분하，수수증기농도증가，반초적비표면적선증대후추우은정。첨가1%O2후，비표면적제승30다배。저농도O2기분하，수O2농도적증가，비표면적정선성증장。갈매전화솔여미공용적화총공용적적비치이급비표면적적관계식위X=0.196(Vm/V)+45.651，X=0.037S+48.066。
Shengli brown coal was gasified by using a laboratory entrained flow reactor at 900℃under the atmospheres of H2O,O2 and their mixture,and pore structure features were investigated. The shapes of adsorption isothermal curves obtained from the chars under various atmospheres were Type II and the shapes of the adsorption loop curves were Type H3. There was a relatively continuous and integral pore system of chars with similar pore structures. Pore diameter distribution was influenced by reaction atmosphere. The quantity of macropores of char was less under all three atmospheres; the order of mesoporesfrom more to less was H2O>O2>H2O+1%O2,and the order of micropores was the reverse. The specific surface area of char presented the trend of increasing at first,then maintaining steady with the increase of H2O. The specific surface area of char during gasification under H2O+1%O2 mixture atmosphere increased by more than 30 times. It increased linearly with the increase of O2 at low concentration of oxygen. The relational expression for conversion versus ratio of micropore volume and total pore volume,and conversion versus specific surface area was X=0.196(Vm/V)+45.651,X=0.037S+48.066.