CAJ | 학술논문

MOFs核壳结构材料是近十几年来化工材料领域的研究热点，其中MOFs可作核，亦可作壳。本文从不同的核出发综述了以 MOFs 为壳的核壳结构材料的合成方法，如外延生长法、后合成修饰法等；概述了其展现出优于核层与壳层的特性（如选择性分离、催化性、磁性等）及以 MOFs 为壳的核壳结构材料在气体吸附、催化剂、磁性分离等应用上的研究，这给MOFs复合材料的产业化带来很大的潜力；而内核主要包括单质金属及非金属类内核、氧化物类内核、MOFs类内核；最后对MOFs为壳的核壳结构复合材料合成方法的改进和拓展、结构均一稳定、多功能化的发展作了展望。
MOFs핵각결구재료시근십궤년래화공재료영역적연구열점，기중MOFs가작핵，역가작각。본문종불동적핵출발종술료이 MOFs 위각적핵각결구재료적합성방법，여외연생장법、후합성수식법등；개술료기전현출우우핵층여각층적특성（여선택성분리、최화성、자성등）급이 MOFs 위각적핵각결구재료재기체흡부、최화제、자성분리등응용상적연구，저급MOFs복합재료적산업화대래흔대적잠력；이내핵주요포괄단질금속급비금속류내핵、양화물류내핵、MOFs류내핵；최후대MOFs위각적핵각결구복합재료합성방법적개진화탁전、결구균일은정、다공능화적발전작료전망。
Core-shell-structure MOFs materials became a hot spot in the field of chemical and materials over the last decade,and MOFs can act as core or shell. This paper mainly reviews the synthesis methods of core-shell-structure material with MOFs as shell according to different nuclear types,such as epitaxial growth method,and post-synthetic modifications;and summarizes the performances which are better than single core or shell,such as separation selectivity,catalysis,magnetic performance, and the development of the core-shell-structure materials with MOFs as shell in gas adsorption, catalysts,magnetic separation,which bring a large potential for MOFs composite industrialization. The cores include metallic and non-metallic element core , oxides core , and MOFs core. And the core-shell-structure composites with MOFs as shell are prospected for the improvement and development of synthesis methods in order to obtain uniform and stable structure and multi-function.