化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2015年
3期
751-757
,共7页
李玉峰%高晓辉%祝晶晶%童丽萍%樊丽权
李玉峰%高曉輝%祝晶晶%童麗萍%樊麗權
리옥봉%고효휘%축정정%동려평%번려권
聚苯胺%聚丙烯酸%聚丙烯酸酯%复合材料%制备
聚苯胺%聚丙烯痠%聚丙烯痠酯%複閤材料%製備
취분알%취병희산%취병희산지%복합재료%제비
polyaniline%polyacrylic%polyacrylate%composites%preparation
聚苯胺/聚丙烯酸(酯)复合材料具有良好的可加工性、成膜性、附着力、电学性能以及防腐蚀性能。本文回顾了国内外在聚苯胺/聚丙烯酸(酯)混合复合材料和聚苯胺/聚丙烯酸(酯)聚合复合材料等方面的研究工作,介绍了各种聚苯胺/聚丙烯酸(酯)复合材料的制备方法、性能及应用,并比较了这些制备方法的优缺点。分析结果表明:混合复合法工艺简单、易于控制、适用范围广;聚合复合法将聚苯胺和聚丙烯酸(酯)在分子水平上结合,使聚苯胺和聚丙烯酸(酯)的优异性能得以综合发挥;而互穿网络聚合法通过网络互穿实现了两种差别较大的分子链的强制相溶。提出在分子水平上的复合是聚苯胺/聚丙烯酸(酯)复合材料研究的主要发展方向。
聚苯胺/聚丙烯痠(酯)複閤材料具有良好的可加工性、成膜性、附著力、電學性能以及防腐蝕性能。本文迴顧瞭國內外在聚苯胺/聚丙烯痠(酯)混閤複閤材料和聚苯胺/聚丙烯痠(酯)聚閤複閤材料等方麵的研究工作,介紹瞭各種聚苯胺/聚丙烯痠(酯)複閤材料的製備方法、性能及應用,併比較瞭這些製備方法的優缺點。分析結果錶明:混閤複閤法工藝簡單、易于控製、適用範圍廣;聚閤複閤法將聚苯胺和聚丙烯痠(酯)在分子水平上結閤,使聚苯胺和聚丙烯痠(酯)的優異性能得以綜閤髮揮;而互穿網絡聚閤法通過網絡互穿實現瞭兩種差彆較大的分子鏈的彊製相溶。提齣在分子水平上的複閤是聚苯胺/聚丙烯痠(酯)複閤材料研究的主要髮展方嚮。
취분알/취병희산(지)복합재료구유량호적가가공성、성막성、부착력、전학성능이급방부식성능。본문회고료국내외재취분알/취병희산(지)혼합복합재료화취분알/취병희산(지)취합복합재료등방면적연구공작,개소료각충취분알/취병희산(지)복합재료적제비방법、성능급응용,병비교료저사제비방법적우결점。분석결과표명:혼합복합법공예간단、역우공제、괄용범위엄;취합복합법장취분알화취병희산(지)재분자수평상결합,사취분알화취병희산(지)적우이성능득이종합발휘;이호천망락취합법통과망락호천실현료량충차별교대적분자련적강제상용。제출재분자수평상적복합시취분알/취병희산(지)복합재료연구적주요발전방향。
Polyaniline/polyacrylic(polyacrylate) composites possess excellent performance of processibility,film-forming properties,adhesion,electrical properties and anti-corrosion properties. In this paper,the research on polyaniline/polyacrylic(polyacrylate) blend composites and polyaniline/polyacrylic (polyacrylate) polymerization composites at home and abroad is reviewed. The preparation methods , properties and applications of various kinds of polyaniline/polyacrylic(polyacrylate) composites are presented. The advantages and disadvantages of these preparation methods are further compared. The blending method is simple and easy to control,so it has wide application. The polymerization method could combine polyaniline with polyacrylic(polyacrylate) at molecular level to improve comprehensive properties. The interpenetrating network polymerization method realizes compatibility of two different molecular chains by network interpenetrating. The paper proposes that composite polyaniline and polyacrylic(polyacrylate) at molecular level is the main development direction in the future.