化学研究与应用
化學研究與應用
화학연구여응용
CHEMICAL RESEARCH AND APPLICATION
2015年
2期
215-219
,共5页
磁性氧化铝球%核壳结构%油柱成型法%孔结构%磁性能
磁性氧化鋁毬%覈殼結構%油柱成型法%孔結構%磁性能
자성양화려구%핵각결구%유주성형법%공결구%자성능
magnetic alumina spheres%core-shell structure%oil column method%pore structure%magnetic properties
采用油柱成型法制备了一种核壳结构磁性氧化铝球,结果表明以球状Fe3 O4为磁核合成的Fe3 O4/SiO2/γ-Al2 O3磁性球在500° C 煅烧下,表面光滑,粒径分布为100~300μm,比表面积为200m2/g,平均孔径为16.8nm,孔容为0.77cm3/g,比饱和磁化强度较高(15.1emu/g),矫顽力和剩磁较低。
採用油柱成型法製備瞭一種覈殼結構磁性氧化鋁毬,結果錶明以毬狀Fe3 O4為磁覈閤成的Fe3 O4/SiO2/γ-Al2 O3磁性毬在500° C 煅燒下,錶麵光滑,粒徑分佈為100~300μm,比錶麵積為200m2/g,平均孔徑為16.8nm,孔容為0.77cm3/g,比飽和磁化彊度較高(15.1emu/g),矯頑力和剩磁較低。
채용유주성형법제비료일충핵각결구자성양화려구,결과표명이구상Fe3 O4위자핵합성적Fe3 O4/SiO2/γ-Al2 O3자성구재500° C 단소하,표면광활,립경분포위100~300μm,비표면적위200m2/g,평균공경위16.8nm,공용위0.77cm3/g,비포화자화강도교고(15.1emu/g),교완력화잉자교저。
Magnetic alumina composite spheres with Fe3 O4 core/Al2 O3 shell structure were prepared by the oil column method. The results show that the specific surface area and pore volume of the spheres calcined at 500°C with smooth surface were 200 m2/g and 0. 77cm3/g,respectively. The distribution of particle size is about 100~200μm,which has high magnetization saturation(15. 1emu/g) ,and low coercivity remanence.