CAJ | 학술논문

金属-有机骨架材料(metal organic frameworks, MOFs)是一类近年来引起研究人员广泛关注和重视的新型多孔有机-无机杂化材料。因结合了有机和无机两种材料, MOFs材料呈现出了优于有机或无机材料的独特性能,如高度发达的孔隙结构、超大的比表面积和良好的化学稳定性等,这些优良性能使其具备了在分析化学中广泛应用的潜力。目前, MOFs材料已经在催化、吸附、药物输送、分离分析等领域被大量研究。本文综述了近几年金属-有机骨架材料在分离分析中的研究进展,介绍了常见的 MOFs 材料的种类及合成方法,重点总结了其在萃取分离、气相色谱固定相和液相色谱固定相中的应用研究,并对其今后的发展进行了展望。
금속-유궤골가재료(metal organic frameworks, MOFs)시일류근년래인기연구인원엄범관주화중시적신형다공유궤-무궤잡화재료。인결합료유궤화무궤량충재료, MOFs재료정현출료우우유궤혹무궤재료적독특성능,여고도발체적공극결구、초대적비표면적화량호적화학은정성등,저사우량성능사기구비료재분석화학중엄범응용적잠력。목전, MOFs재료이경재최화、흡부、약물수송、분리분석등영역피대량연구。본문종술료근궤년금속-유궤골가재료재분리분석중적연구진전,개소료상견적 MOFs 재료적충류급합성방법,중점총결료기재췌취분리、기상색보고정상화액상색보고정상중적응용연구,병대기금후적발전진행료전망。
ABSTRACT:Metal-organic frameworks (MOFs) are a novelty class of organic-inorganic hybrid materials. Since being proposed, MOFs materials have been obtaining more and more attentions of researchers in recent years. Because of the combination of the properties of organic materials and inorganic materials, MOFs materials have better performances, such as highly developed pore structure, large specific surface area, excellent chemical stability, and so on. These materials provide excellence properties suitable for analytical chemistry. At the moment, MOFs have been applied in the field of catalysis, adsorption, separation, and so on. This paper reviewed the progress on MOFs for the separation and analysis in the past few years. Common MOFs materials and their synthesis methods were introduced. The focusing points were the application of MOFs materials as extraction separation materials, stationary phase in gas chromatography and stationary phase in liquid chromatography. Finally, the future application of MOFs materials in separation and analysis was given.