CAJ | 학술논문

综述了离子液体作为溶剂、单体、引发剂或配体参与原子转移自由基聚合。离子液体具有独特的物理化学性能，可作为溶剂或配体直接参与聚合反应，也可以通过化学修饰合成离子液体型聚合单体或引发剂，利用ATRP技术制备出含有聚合离子液体链段或端基的功能性高分子材料。这种材料可应用于太阳能电池、聚合物电池、光敏元件、吸附剂或传感元件等多个领域，成为高分子材料研究领域的一个重要课题。
종술료리자액체작위용제、단체、인발제혹배체삼여원자전이자유기취합。리자액체구유독특적물이화학성능，가작위용제혹배체직접삼여취합반응，야가이통과화학수식합성리자액체형취합단체혹인발제，이용ATRP기술제비출함유취합리자액체련단혹단기적공능성고분자재료。저충재료가응용우태양능전지、취합물전지、광민원건、흡부제혹전감원건등다개영역，성위고분자재료연구영역적일개중요과제。
Ionic liquid as solvent,monomer,initiator or ligand involved in atom transfer radical polymeriza-tion were reviewed,ionic liquid has unique physical and chemical properties. Especially,the functional polymers,with ionic-liquid chains or end-groups,were prepared by ATRP with ionic liquid monomers or initiators synthesized by chemical modification of some ionic liquid molecules. These functional polymers have been an intensive field of research in materials science recently,because of their potential applica-tions in fields as solar battery,polymer battery,photosensitive devices,adsorbent or sensing elements.