CAJ | 학술논문

用不同功能化的纳米石墨粉改性CMC-PVA/CS-PVA双极膜。研究表明，改性可促进膜中间界面层水的解离，提高水解离效率，降低槽电压与膜阻抗。其促进水解离能力大小顺序为：CNPs-SO3 H ﹥ CNPs-COOH ﹥未功能化的CNPs。此外，纳米石墨粉的添加量对膜的综合性能有影响，最佳添加量为膜层材料质量的0.9%。
용불동공능화적납미석묵분개성CMC-PVA/CS-PVA쌍겁막。연구표명，개성가촉진막중간계면층수적해리，제고수해리효솔，강저조전압여막조항。기촉진수해리능력대소순서위：CNPs-SO3 H ﹥ CNPs-COOH ﹥미공능화적CNPs。차외，납미석묵분적첨가량대막적종합성능유영향，최가첨가량위막층재료질량적0.9%。
The CMC-PVA/CS-PVA bipolar membrane( BPM ) was modified by the functionalized nano graphite powders( CNPs). The studies showed that the modification could promote the water dissociation at the interlayer,improve the water dissociation efficiency and reduce the cell voltage and membrane im-pedance. For the different functional CNPs,the order of the ability to promote water dissociation was as following:CNPs-SO3 H﹥CNPs-COOH﹥CNPs. Furthermore,the addition amount of the CNPs had an im-pact on the overall performance of the BPM,and the optimal amount was 0. 9% of the membrane material mass.