CAJ | 학술논문

以手性化合物苯丙氨酸作为前驱体，于油酸中通过高温溶剂法一步合成了具有强疏水性的白色类多肽聚合物，扫描电子显微镜分析表明，产物自组装成纳米棒结构。利用核磁共振、紫外光谱、红外光谱、荧光光谱、基质辅助激光解析电离飞行时间质谱等对产物进行了分析。圆二色光谱分析表明，产物仍具有手性性质。该合成方法简单方便，提供了一种合成类多肽聚合物的途径。
이수성화합물분병안산작위전구체，우유산중통과고온용제법일보합성료구유강소수성적백색류다태취합물，소묘전자현미경분석표명，산물자조장성납미봉결구。이용핵자공진、자외광보、홍외광보、형광광보、기질보조격광해석전리비행시간질보등대산물진행료분석。원이색광보분석표명，산물잉구유수성성질。해합성방법간단방편，제공료일충합성류다태취합물적도경。
White hydrophobic peptide-like polymer was prepared from phenylalanine by one-step solvo-thermal method with oleic acid as reaction media. SEM images showed that the product can simultaneously self-assemble to form nanorod structure under this condition. The as-prepared product was further charac-terized by NMR,UV-Vis spectroscopy,IR spectroscopy,fluorescence spectroscopy,and matrix assisted la-ser desorption ionization/time of flight( MALDI-TOF)mass spectroscopy. The circular dichroism spectra showed that the obtained polymer still possessed chirality property. The facile method provides an ap-proach to synthesize peptide-like polymer.