化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2015年
3期
1194-1200
,共7页
南辉%王冲%王刚%林红%韦浩民%王子玲
南輝%王遲%王剛%林紅%韋浩民%王子玲
남휘%왕충%왕강%림홍%위호민%왕자령
碳纳米管%多孔介质%纳米结构%吸收
碳納米管%多孔介質%納米結構%吸收
탄납미관%다공개질%납미결구%흡수
carbon nanotubes%porous media%nanostructure%adsorption
采用环氧树脂作为前驱体溶胶,利用负载有碳纳米管的铝板为接收基板,通过简单方便的静电纺丝协同拉拔技术,宏量制备了碳纳米管/环氧树脂复合纤维棉,并对这种复合纤维棉的吸油性能进行了探索。采用扫描电子显微镜(SEM)、热重分析仪(TGA)、压汞仪、拉曼光谱仪等设备系统分析了复合纤维棉的形貌、结构和组成。结果表明,复合纤维棉具有高的比表面积与孔隙率,碳纳米管均匀地分布在复合纤维棉中。复合纤维棉与水和植物油的接触角分别为114.1°与66.8°;与丙纶纤维相比较,复合纤维棉展现出更加优异的吸油能力,可吸附超过自身质量10倍的油类物质。
採用環氧樹脂作為前驅體溶膠,利用負載有碳納米管的鋁闆為接收基闆,通過簡單方便的靜電紡絲協同拉拔技術,宏量製備瞭碳納米管/環氧樹脂複閤纖維棉,併對這種複閤纖維棉的吸油性能進行瞭探索。採用掃描電子顯微鏡(SEM)、熱重分析儀(TGA)、壓汞儀、拉曼光譜儀等設備繫統分析瞭複閤纖維棉的形貌、結構和組成。結果錶明,複閤纖維棉具有高的比錶麵積與孔隙率,碳納米管均勻地分佈在複閤纖維棉中。複閤纖維棉與水和植物油的接觸角分彆為114.1°與66.8°;與丙綸纖維相比較,複閤纖維棉展現齣更加優異的吸油能力,可吸附超過自身質量10倍的油類物質。
채용배양수지작위전구체용효,이용부재유탄납미관적려판위접수기판,통과간단방편적정전방사협동랍발기술,굉량제비료탄납미관/배양수지복합섬유면,병대저충복합섬유면적흡유성능진행료탐색。채용소묘전자현미경(SEM)、열중분석의(TGA)、압홍의、랍만광보의등설비계통분석료복합섬유면적형모、결구화조성。결과표명,복합섬유면구유고적비표면적여공극솔,탄납미관균균지분포재복합섬유면중。복합섬유면여수화식물유적접촉각분별위114.1°여66.8°;여병륜섬유상비교,복합섬유면전현출경가우이적흡유능력,가흡부초과자신질량10배적유류물질。
Carbon nanotubes/epoxy resin (EP) cellucotton composite was prepared on a large scale using EP as the precursor sol, aluminum plates covered with carbon nanotubes as substrate, by a simple and convenient electrospinning and collaborative pulling technology. The morphology, structure and composition of the obtained samples were investigated with scanning electron microscopy, thermogravimetric analyzer, mercury injection test and Raman spectroscopy. Carbon nanotubes were partly wrapped and distributed evenly on the surface of the EP fibers, and the composite structures had high specific surface area and porosity. The contact angle of the carbon nanotube/EP composite structure was 114.1° for water, and 66.8° for vegetable oil. The as-made carbon nanotubes/EP composites showed superior adsorption capacity for vegetable oil, which was better than polypropylene fiber, and could adsorb more than 10 times of oil in terms of their own mass.