中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2015年
1期
125-132
,共8页
镁合金%铈转化膜%腐蚀行为%腐蚀机理
鎂閤金%鈰轉化膜%腐蝕行為%腐蝕機理
미합금%시전화막%부식행위%부식궤리
magnesium alloy%cerium conversion coating%corrosion behavior%corrosion mechanism
通过静态浸泡腐蚀实验,采用扫描电子显微镜、X射线能谱仪、电化学实验等研究镁合金铈转化膜在0.05 mol/L NaCl溶液中的腐蚀行为,探讨膜层腐蚀机理。结果表明:随着浸泡时间的延长,膜层发生腐蚀和遭到破坏的程度也随之增强,浸泡初级腐蚀产物组织疏松,腐蚀后期腐蚀产物的致密性和紧实度增加;腐蚀产物主要由镁、氧等元素组成。随浸泡时间的延长,膜层电阻和腐蚀电位先增大后减小,腐蚀电流密度呈现先减小后增大的趋势。
通過靜態浸泡腐蝕實驗,採用掃描電子顯微鏡、X射線能譜儀、電化學實驗等研究鎂閤金鈰轉化膜在0.05 mol/L NaCl溶液中的腐蝕行為,探討膜層腐蝕機理。結果錶明:隨著浸泡時間的延長,膜層髮生腐蝕和遭到破壞的程度也隨之增彊,浸泡初級腐蝕產物組織疏鬆,腐蝕後期腐蝕產物的緻密性和緊實度增加;腐蝕產物主要由鎂、氧等元素組成。隨浸泡時間的延長,膜層電阻和腐蝕電位先增大後減小,腐蝕電流密度呈現先減小後增大的趨勢。
통과정태침포부식실험,채용소묘전자현미경、X사선능보의、전화학실험등연구미합금시전화막재0.05 mol/L NaCl용액중적부식행위,탐토막층부식궤리。결과표명:수착침포시간적연장,막층발생부식화조도파배적정도야수지증강,침포초급부식산물조직소송,부식후기부식산물적치밀성화긴실도증가;부식산물주요유미、양등원소조성。수침포시간적연장,막층전조화부식전위선증대후감소,부식전류밀도정현선감소후증대적추세。
The corrosion behavior and corrosion mechanism of the cerium conversion coating on magnesium alloy in 0.05 mol/L NaCl solution were investigated by using static immersing corrosion test, scanning electron microscope, energy dispersive spectrometer and electrochemical methods. The results show that with increasing the immersion time, the corrosion and damage degree of coating increase. The initial corrosion product is loose and the density and compactness of the coating corrosion products of coating increase, the main compositions of corrosion product, are Mg and O elements. The film resistance and corrosion potential increase at the first stage, and then decrease with increasing the immersion time, while the corrosion current density changes in the opposite tendency.