光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2015年
2期
293-297
,共5页
王蒙%王斌%付苏阳%孙希鹏%黄森鹏%郭廷珂%李昊宇%徐晓轩%王玉芳
王矇%王斌%付囌暘%孫希鵬%黃森鵬%郭廷珂%李昊宇%徐曉軒%王玉芳
왕몽%왕빈%부소양%손희붕%황삼붕%곽정가%리호우%서효헌%왕옥방
周期微结构%局域场增强%共振波长调控%表面等离激元共振
週期微結構%跼域場增彊%共振波長調控%錶麵等離激元共振
주기미결구%국역장증강%공진파장조공%표면등리격원공진
Periodic nanostructure%Localized field enhancement%Tuning of resonant wavelength%Surface plasmon resonance
基于表面等离激元共振(SPR)的原理,设计了一种具有矩形凹槽周期阵列微结构的金属增强基底。利用有限元方法对基底表面附近电场的分布进行了理论模拟分析,结果表明在SPR共振情况下,其凹槽微结构坑口处可得到强局域场,局域电场强度Emax/E0可达20。通过改变结构的周期、凹槽长度l、宽度ω以及环境介质,SPR共振峰发生规律性的移动,波长覆盖范围为500~1000 nm。入射光沿x方向偏振的情况下,随着结构x方向周期Px 的增加,SPR共振峰明显红移。当入射光波长与Px 相当时,观察到凹槽内局域电场突然减小的现象。这是由于满足了波矢匹配条件,传播型SPP被激发导致的。改变凹槽长度l,发现共振波长随l的增加红移,近似呈线性关系。环境介质折射率的增加也会引起共振峰的红移。而凹槽宽度ω的增加将导致其蓝移。这种规律性的移动为实现共振波长的调控提供了途径。受Jain研究报道的启发,矩形凹槽结构可以等效为两对偶极耦合模型的组合,从而解释SPR共振峰随结构参数变化而发生的移动。
基于錶麵等離激元共振(SPR)的原理,設計瞭一種具有矩形凹槽週期陣列微結構的金屬增彊基底。利用有限元方法對基底錶麵附近電場的分佈進行瞭理論模擬分析,結果錶明在SPR共振情況下,其凹槽微結構坑口處可得到彊跼域場,跼域電場彊度Emax/E0可達20。通過改變結構的週期、凹槽長度l、寬度ω以及環境介質,SPR共振峰髮生規律性的移動,波長覆蓋範圍為500~1000 nm。入射光沿x方嚮偏振的情況下,隨著結構x方嚮週期Px 的增加,SPR共振峰明顯紅移。噹入射光波長與Px 相噹時,觀察到凹槽內跼域電場突然減小的現象。這是由于滿足瞭波矢匹配條件,傳播型SPP被激髮導緻的。改變凹槽長度l,髮現共振波長隨l的增加紅移,近似呈線性關繫。環境介質摺射率的增加也會引起共振峰的紅移。而凹槽寬度ω的增加將導緻其藍移。這種規律性的移動為實現共振波長的調控提供瞭途徑。受Jain研究報道的啟髮,矩形凹槽結構可以等效為兩對偶極耦閤模型的組閤,從而解釋SPR共振峰隨結構參數變化而髮生的移動。
기우표면등리격원공진(SPR)적원리,설계료일충구유구형요조주기진렬미결구적금속증강기저。이용유한원방법대기저표면부근전장적분포진행료이론모의분석,결과표명재SPR공진정황하,기요조미결구갱구처가득도강국역장,국역전장강도Emax/E0가체20。통과개변결구적주기、요조장도l、관도ω이급배경개질,SPR공진봉발생규률성적이동,파장복개범위위500~1000 nm。입사광연x방향편진적정황하,수착결구x방향주기Px 적증가,SPR공진봉명현홍이。당입사광파장여Px 상당시,관찰도요조내국역전장돌연감소적현상。저시유우만족료파시필배조건,전파형SPP피격발도치적。개변요조장도l,발현공진파장수l적증가홍이,근사정선성관계。배경개질절사솔적증가야회인기공진봉적홍이。이요조관도ω적증가장도치기람이。저충규률성적이동위실현공진파장적조공제공료도경。수Jain연구보도적계발,구형요조결구가이등효위량대우겁우합모형적조합,종이해석SPR공진봉수결구삼수변화이발생적이동。
The authors have designed a novel type of periodic rectangular pit nanostructure substrate based on the surface plas-mon principle.Finite element method was employed to simulate the optical near-field distribution.Strongly enhanced field whose electric intensity Emax/E0 can be as high as 20 at resonance frequency appears around pithead of the periodic structure.As the pe-riod of structure,pit length l,widthωand environment change,the authors observe the regular shifting of plasmon resonant wavelength which can cover the range from 500 to 1 000 nm.The red shifts of SPR resonance peaks are increased with the incre-ment of period Px when incident light is polarized along x axis.An abrupt decrease in localized electric field in the pit is observed as incident wavelength approaches Px .This is due to the satisfaction of wave vector matching condition and the excitation of propagating SPP.SPR resonance peaks also red shifts with the increment on pit length l and environment dielectric refractive in-dex,presenting a linear dependence with pit length l.While the resonance peaks are blue shifted with the increment of pit widthω.The results presented in this paper will provide a way to tune the plasmon resonant wavelength.Inspired by Jain’s report, SPR resonance peaks’shifting with the changing of structure parameters can be explained by viewing the rectangular pit nano-structure as combination of two pairs of dipole-dipole coupling models along x and y axis respectively.