中国煤炭地质
中國煤炭地質
중국매탄지질
COAL GEOLOGY OF CHINA
2015年
1期
18-21
,共4页
姜迪%王绍清%韩林璞%陈华奇%王宇
薑迪%王紹清%韓林璞%陳華奇%王宇
강적%왕소청%한림박%진화기%왕우
树皮煤%树皮体%热解%升温速率%热重分析
樹皮煤%樹皮體%熱解%升溫速率%熱重分析
수피매%수피체%열해%승온속솔%열중분석
bark coal%barkinite%pyrolysis%heating rate%thermogravimetric analysis
中国特有煤种——树皮煤,因具有高氢、高挥发分及高焦油产率等特点而备受关注,而其中富含的特殊显微组分——树皮体,其热性质一直未得到深入研究,直接影响树皮煤的合理利用。采用热重分析仪对不同升温速率下树皮体、镜质体及原煤(树皮煤)的热解失重特征进行了对比研究,并结合工业分析和元素分析结果,讨论了树皮体的化学性质。研究表明:随着升温速率的增加,树皮体、镜质体和树皮煤的TG和DTG曲线均不同程度的向右侧高温区移动,最大失重速率相应减小,升温速率对树皮体的DTG曲线变化影响较大。尽管使用的升温速率不同,而树皮体的DTG曲线峰形均具有窄而尖的特点,说明树皮体的受热变化比较剧烈。同时,树皮体的总失重量均大于镜质体和树皮煤。
中國特有煤種——樹皮煤,因具有高氫、高揮髮分及高焦油產率等特點而備受關註,而其中富含的特殊顯微組分——樹皮體,其熱性質一直未得到深入研究,直接影響樹皮煤的閤理利用。採用熱重分析儀對不同升溫速率下樹皮體、鏡質體及原煤(樹皮煤)的熱解失重特徵進行瞭對比研究,併結閤工業分析和元素分析結果,討論瞭樹皮體的化學性質。研究錶明:隨著升溫速率的增加,樹皮體、鏡質體和樹皮煤的TG和DTG麯線均不同程度的嚮右側高溫區移動,最大失重速率相應減小,升溫速率對樹皮體的DTG麯線變化影響較大。儘管使用的升溫速率不同,而樹皮體的DTG麯線峰形均具有窄而尖的特點,說明樹皮體的受熱變化比較劇烈。同時,樹皮體的總失重量均大于鏡質體和樹皮煤。
중국특유매충——수피매,인구유고경、고휘발분급고초유산솔등특점이비수관주,이기중부함적특수현미조분——수피체,기열성질일직미득도심입연구,직접영향수피매적합리이용。채용열중분석의대불동승온속솔하수피체、경질체급원매(수피매)적열해실중특정진행료대비연구,병결합공업분석화원소분석결과,토론료수피체적화학성질。연구표명:수착승온속솔적증가,수피체、경질체화수피매적TG화DTG곡선균불동정도적향우측고온구이동,최대실중속솔상응감소,승온속솔대수피체적DTG곡선변화영향교대。진관사용적승온속솔불동,이수피체적DTG곡선봉형균구유착이첨적특점,설명수피체적수열변화비교극렬。동시,수피체적총실중량균대우경질체화수피매。
The bark coal, a Chinese proper coal rank has been aroused general concern because of its high hydrogen, high volatile mat?ter contents and high tar yield characteristics. But the thermal properties of the rich special maceral—barkinite have not been studied further all the time, thus directly impacted the rational use of bark coal. Using thermogravimetric analyzer carried out comparative study of barkinite, vitrinite and raw coal (bark coal) pyrolytic weight loss characteristics under different heating rates, combined with proximate and ultimate analyses results discussed chemical properties of barkinite. The study has shown that along with the increasing of heating rate, the TG and DTG curves of barkinite, vitrinite and bark coal are all migrating to right side high temperature zone in vary?ing degrees;maximum weight loss rate decreasing correspondingly;heating rate has greater impact on barkinite DTG curves. Though under different heating rates, barkinite DTG curve peaks are all distinguished by narrow and acuminated shapes thus explained the rather acute barkinite heating variation. Moreover, the total weight loss of barkinite is greater than both vitrinite and bark coal.