功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2015年
5期
5084-5088,5094
,共6页
黄振楠%寇生中%金东东%杨杭生%张孝彬
黃振楠%寇生中%金東東%楊杭生%張孝彬
황진남%구생중%금동동%양항생%장효빈
超级电容器%氢氧化镍%还原氧化石墨烯
超級電容器%氫氧化鎳%還原氧化石墨烯
초급전용기%경양화얼%환원양화석묵희
supercapacitor%Ni(OH)2%reduced graphene oxides
采用共沉淀法制备了氢氧化镍/还原氧化石墨烯复合材料,并以此为电极研究了其超级电容性能.实验发现,六方氢氧化镍纳米片被成功插入到还原氧化石墨烯的层间,这有效抑制了还原氧化石墨烯和氢氧化镍的团聚,提高了电极的稳定性.当氢氧化镍和还原氧化石墨烯的质量比为5.5∶1时,显示了最佳的电化学性能:在-0.1~0.37 V 的电位窗口,1 A/g 的电流密度下,比电容高达1036 F/g;4 A/g 的电流密度下快速循环3000次后,仍然保持70%的比电容.
採用共沉澱法製備瞭氫氧化鎳/還原氧化石墨烯複閤材料,併以此為電極研究瞭其超級電容性能.實驗髮現,六方氫氧化鎳納米片被成功插入到還原氧化石墨烯的層間,這有效抑製瞭還原氧化石墨烯和氫氧化鎳的糰聚,提高瞭電極的穩定性.噹氫氧化鎳和還原氧化石墨烯的質量比為5.5∶1時,顯示瞭最佳的電化學性能:在-0.1~0.37 V 的電位窗口,1 A/g 的電流密度下,比電容高達1036 F/g;4 A/g 的電流密度下快速循環3000次後,仍然保持70%的比電容.
채용공침정법제비료경양화얼/환원양화석묵희복합재료,병이차위전겁연구료기초급전용성능.실험발현,륙방경양화얼납미편피성공삽입도환원양화석묵희적층간,저유효억제료환원양화석묵희화경양화얼적단취,제고료전겁적은정성.당경양화얼화환원양화석묵희적질량비위5.5∶1시,현시료최가적전화학성능:재-0.1~0.37 V 적전위창구,1 A/g 적전류밀도하,비전용고체1036 F/g;4 A/g 적전류밀도하쾌속순배3000차후,잉연보지70%적비전용.
In this paper,composites of Ni(OH)2/reduced graphene oxides (rGO)were prepared by chemical co-precipitation method,by which Ni(OH)2 hexagonal nanoplates were successfully inserted into the layers of re-duced graphene oxides.As a result,the aggregation of rGO and Ni(OH)2 is efficiently prevented and the stabili-ty of the composites are also improved.The electrochemical performance of Ni(OH)2/rGO is further investiga-ted as electrode materials for supercapacitors.We find that when the mass ratio of Ni(OH)2 to rGO is 5.5∶1, the composites achieve the best electrochemical performance (optimal specific capacitance of 1 036 F/g has been achieved at a current density of 1 A/g).In addition,the value of capacitance retention is above 70% after 3 000 cycles at the current density of 4 A/g.