工程塑料应用
工程塑料應用
공정소료응용
ENGINEERING PLASTICS APPLICATION
2015年
1期
16-19
,共4页
陈雷%杨斌%曹明%苗继斌%夏茹%钱家盛%章于川
陳雷%楊斌%曹明%苗繼斌%夏茹%錢傢盛%章于川
진뢰%양빈%조명%묘계빈%하여%전가성%장우천
β成核剂%PP/EPDM复合材料%固化行为%结晶速率
β成覈劑%PP/EPDM複閤材料%固化行為%結晶速率
β성핵제%PP/EPDM복합재료%고화행위%결정속솔
β-nucleating agent%PP/EPDM composite%solidification behavior%crystallization rate
分别以β成核剂二苯基己二酞二胺(NT–C)和芳酰胺类化合物(TMB–5)增韧 PP/EPDM 复合材料,制备了 PP/EPDM/NT–C 复合材料与 PP/EPDM/TMB–5复合材料。研究了β成核剂与 EPDM 的协同增韧效应,以及两种β成核剂对 PP/EPDM 复合材料固化行为及结晶行为的影响。结果表明,在 TMB–5含量相同时,随着 EPDM含量的增加,PP/EPDM/TMB–5结晶速率先增大后减小,在 EPDM 质量分数为10%时达到最佳。在 EPDM 含量相同时,随着 NT–C 含量的增加,PP/EPDM/NT–C 复合材料的结晶速率逐渐提高。
分彆以β成覈劑二苯基己二酞二胺(NT–C)和芳酰胺類化閤物(TMB–5)增韌 PP/EPDM 複閤材料,製備瞭 PP/EPDM/NT–C 複閤材料與 PP/EPDM/TMB–5複閤材料。研究瞭β成覈劑與 EPDM 的協同增韌效應,以及兩種β成覈劑對 PP/EPDM 複閤材料固化行為及結晶行為的影響。結果錶明,在 TMB–5含量相同時,隨著 EPDM含量的增加,PP/EPDM/TMB–5結晶速率先增大後減小,在 EPDM 質量分數為10%時達到最佳。在 EPDM 含量相同時,隨著 NT–C 含量的增加,PP/EPDM/NT–C 複閤材料的結晶速率逐漸提高。
분별이β성핵제이분기기이태이알(NT–C)화방선알류화합물(TMB–5)증인 PP/EPDM 복합재료,제비료 PP/EPDM/NT–C 복합재료여 PP/EPDM/TMB–5복합재료。연구료β성핵제여 EPDM 적협동증인효응,이급량충β성핵제대 PP/EPDM 복합재료고화행위급결정행위적영향。결과표명,재 TMB–5함량상동시,수착 EPDM함량적증가,PP/EPDM/TMB–5결정속솔선증대후감소,재 EPDM 질량분수위10%시체도최가。재 EPDM 함량상동시,수착 NT–C 함량적증가,PP/EPDM/NT–C 복합재료적결정속솔축점제고。
Diphenyl phthalate diamine (NT–C) and aryl dicarboxylic acid amide (TMB–5) were adopted to toughen PP/EPDM composites. Both PP/EPDM/NT–C and PP/EPDM/TMB–5 composites were prepared. The synergistic toughening effect of β–form nucleating agent and EPDM was investigated, together with the influence of two β–form nucleating agents on solidification and crystallization behaviors of PP/EPDM composites. The results show that for given TMB–5 content, the crystallization rate of PP/EPDM/TMB–5 composites initially increase and then decrease with EPDM content increasing. When the content of EPDM is 10%, the crystallization rate of PP/EPDM/TMB–5 composites is the highest. For given EPDM content, the crystallization rate of PP/EPDM/NT–C composites gradually increase with the increase of NT–C content.