化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2015年
2期
18-24
,共7页
杨佳霖%杜小泽%杨立军%杨勇平
楊佳霖%杜小澤%楊立軍%楊勇平
양가림%두소택%양립군%양용평
相变%多孔介质%泡沫金属%自然对流%可视化实验
相變%多孔介質%泡沫金屬%自然對流%可視化實驗
상변%다공개질%포말금속%자연대류%가시화실험
phase change%porous media%metal foam%natural convection%visualization
相变材料的低热导率是限制潜热蓄热广泛应用的重要原因。将相变材料石蜡真空条件下注入到泡沫金属铜内制备泡沫金属铜-石蜡复合相变材料,通过铜的高热导率及高孔隙材料的大面体比来强化相变换热过程。采用DSC 示差扫描量热法对石蜡进行热物性测量获得准确的石蜡相变温度及相变潜热。以管壳式相变蓄热结构为对象,提取对称结构进行可视化设计,对比纯石蜡及泡沫金属铜-石蜡复合材料在相同运行条件下的相变过程,追踪二者熔化过程的相界面位置随时间的演化过程并布置热电偶准确测量材料内部的温度分布。结果显示加入泡沫金属后的复合材料的内部温差明显减小,温度分布均匀,蓄热热通量显著增大,有效缩短相变时间并缓解了自然对流造成的顶部过热和底部不熔化现象。
相變材料的低熱導率是限製潛熱蓄熱廣汎應用的重要原因。將相變材料石蠟真空條件下註入到泡沫金屬銅內製備泡沫金屬銅-石蠟複閤相變材料,通過銅的高熱導率及高孔隙材料的大麵體比來彊化相變換熱過程。採用DSC 示差掃描量熱法對石蠟進行熱物性測量穫得準確的石蠟相變溫度及相變潛熱。以管殼式相變蓄熱結構為對象,提取對稱結構進行可視化設計,對比純石蠟及泡沫金屬銅-石蠟複閤材料在相同運行條件下的相變過程,追蹤二者鎔化過程的相界麵位置隨時間的縯化過程併佈置熱電偶準確測量材料內部的溫度分佈。結果顯示加入泡沫金屬後的複閤材料的內部溫差明顯減小,溫度分佈均勻,蓄熱熱通量顯著增大,有效縮短相變時間併緩解瞭自然對流造成的頂部過熱和底部不鎔化現象。
상변재료적저열도솔시한제잠열축열엄범응용적중요원인。장상변재료석사진공조건하주입도포말금속동내제비포말금속동-석사복합상변재료,통과동적고열도솔급고공극재료적대면체비래강화상변환열과정。채용DSC 시차소묘량열법대석사진행열물성측량획득준학적석사상변온도급상변잠열。이관각식상변축열결구위대상,제취대칭결구진행가시화설계,대비순석사급포말금속동-석사복합재료재상동운행조건하적상변과정,추종이자용화과정적상계면위치수시간적연화과정병포치열전우준학측량재료내부적온도분포。결과현시가입포말금속후적복합재료적내부온차명현감소,온도분포균균,축열열통량현저증대,유효축단상변시간병완해료자연대류조성적정부과열화저부불용화현상。
Latent heat thermal energy storage technology is a promising option for future cost reduction in parabolic trough power system, however, low thermal conductivity of phase change material (PCM) is the major shortage leading to large temperature difference between heat transfer surface and solid-liquid interface of the PCM, and low energy storage rate. A charging experimental system was set up for testing the dynamic thermal behavior of phase change material in metal foam. Paraffin wax is used as PCM and its thermal properties were determined with differential scanning calorimetry (DSC). Metal foam was made of red copper. The sample of PCM-foam composite with semi-circular slot was placed inside a transparent cuboid Plexiglas enclosure, and a copper tube with the same radius as the semi-circular slot was in close bonding with the PCM-foam composite. High temperature water flowed through the copper tube as the heat transfer fluid (HTF) heating the composite material. The temperature field and melting process of PCM at pore size were studied using appropriate thermocouple and high definition camera. Thermal characteristics, including temperature profiles and position of solid/liquid interface were investigated and recorded, and the effects of heating temperature and flow rate of HTF on temperature uniformity and melting rate were documented and discussed. Metal foam could effectively improve heat transfer performance of PCM and decrease charging time Temperature difference was smaller and heating flux was larger in the composite than those in pure paraffin.