CAJ | 학술논문

金属基钯复合膜长期处于高温下会发生金属间相扩散问题,严重影响复合膜的使用寿命。运用化学镀的方法,在不同材料的多孔金属支撑体表面制备钯膜,然后对钯复合膜进行惰性气体保护下的高温热处理。运用背散射和能谱线扫描的方法分析、表征所制备的各种钯复合膜的元素分布状况,并且将金属基钯复合膜与 Pd/陶瓷复合膜相对比,研究前者的相扩散程度。结果表明,在测试的温度范围内(500~700℃),没有发现 Pd/Ti 复合膜、Pd/Ti-Al 合金复合膜发生相扩散现象,Pd/PSS(多孔不锈钢)复合膜经历700℃、40 h 的高温热处理后发生了严重的金属间相扩散现象。
금속기파복합막장기처우고온하회발생금속간상확산문제,엄중영향복합막적사용수명。운용화학도적방법,재불동재료적다공금속지탱체표면제비파막,연후대파복합막진행타성기체보호하적고온열처리。운용배산사화능보선소묘적방법분석、표정소제비적각충파복합막적원소분포상황,병차장금속기파복합막여 Pd/도자복합막상대비,연구전자적상확산정도。결과표명,재측시적온도범위내(500~700℃),몰유발현 Pd/Ti 복합막、Pd/Ti-Al 합금복합막발생상확산현상,Pd/PSS(다공불수강)복합막경력700℃、40 h 적고온열처리후발생료엄중적금속간상확산현상。
Inter-metal diffusion phenomenon will happen when metal matrix Pd-composite membranes are under high temperature for a long time,which will influence the service life of the Pd-composite membrane.By electroless plating,the palladium membrane on the surface of the porous metal supporter with different materials was prepared.And the Pd-composite membranewas then heat treatment under high temperature in inert gas.Backscattered Electron Microscopy (BSE)and Energy Dispersive Spectrometer (EDS)cross-sectional line scans were used to analysis the elements distribution of various Pd-composite membranes,and the diffusion level of the metal matrix Pd-composite membrane was studied by comparing it with the ceramic composite membrane.The results showed that there was no diffusion phenomenon happening to Pd/titanium (Ti) composite membranes and Pd/titanium-aluminum (Ti-Al)alloy composite membranes in the temperature range of 500 to 700℃,while serious inter-metal diffusion phenomenon happened when Pd/porous-stainless-steel (PSS)composite membrane was under high temperature heat treatment (700 ℃)for 40 hours.