化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2015年
2期
474-478
,共5页
刘军霞%姚庆鑫%杨金%周磊%谢建军
劉軍霞%姚慶鑫%楊金%週磊%謝建軍
류군하%요경흠%양금%주뢰%사건군
三聚氰胺甲醛树脂%泡沫%优化%制备%正交实验
三聚氰胺甲醛樹脂%泡沫%優化%製備%正交實驗
삼취청알갑철수지%포말%우화%제비%정교실험
melamine-formaldehyde resin%foam%optimization%preparation%orthogonal experiment
用己内酰胺作改性剂,通过正交实验设计考察了甲醛和三聚氰胺摩尔比(F/M)、溶液pH值、反应温度(T)和反应时间(t)对可发性三聚氰胺甲醛(MF)树脂的储存期、固含量、黏度、MF泡沫密度及泡孔尺寸均匀性的影响,运用综合评分法和综合平衡法对正交实验结果进行了分析,得出最优水平组合:F/M=2.5,pH=8.0,T=90℃,t=60min。最优条件下合成的MF树脂可发泡性良好,制得的泡沫性能优良。
用己內酰胺作改性劑,通過正交實驗設計攷察瞭甲醛和三聚氰胺摩爾比(F/M)、溶液pH值、反應溫度(T)和反應時間(t)對可髮性三聚氰胺甲醛(MF)樹脂的儲存期、固含量、黏度、MF泡沫密度及泡孔呎吋均勻性的影響,運用綜閤評分法和綜閤平衡法對正交實驗結果進行瞭分析,得齣最優水平組閤:F/M=2.5,pH=8.0,T=90℃,t=60min。最優條件下閤成的MF樹脂可髮泡性良好,製得的泡沫性能優良。
용기내선알작개성제,통과정교실험설계고찰료갑철화삼취청알마이비(F/M)、용액pH치、반응온도(T)화반응시간(t)대가발성삼취청알갑철(MF)수지적저존기、고함량、점도、MF포말밀도급포공척촌균균성적영향,운용종합평분법화종합평형법대정교실험결과진행료분석,득출최우수평조합:F/M=2.5,pH=8.0,T=90℃,t=60min。최우조건하합성적MF수지가발포성량호,제득적포말성능우량。
The effects of mole ratio of formaldehyde and melamine (F/M),solution pH,reaction temperature (T) and time (t) on the properties of foaming melamine-formaldehyde (MF) resin with caprolactam as modifier were investigated by orthogonal experiment where solid content,viscosity and storage time of the MF resin,density and size uniformity of the MF foam were used as performance evaluation parameters. The results of the experiments were analyzed by using the comprehensive scoring method and the integrated balance method. The optimum formula of preparation was obtained as follows:F/M= 2.5,pH=8.0,T=90℃,t=60min. The MF resin prepared under the optimal conditions could be foamed well and the properties of the foam were good.