CAJ | 학술논문

根据环糊精衍生物分子结构与形态的不同，分类综述了环糊精衍生物（以β-环糊精衍生物为主）的形态及其构筑策略研究进展，包括单取代环糊精衍生物、双取代环糊精衍生物、多取代环糊精衍生物、二聚体环糊精衍生物、多聚体环糊精衍生物和环糊精聚合物（包括固载化环糊精）。指出环糊精衍生物的构筑是基于环糊精构筑各种功能材料的基础与关键，是环糊精母体应用的进一步拓展。基于环糊精构筑各种超分子仿酶，不仅可以充分发挥环糊精结构上的先天优势，也可以实现有机合成反应从有机相到水相的顺利过渡，并提高反应的选择性，对有机合成化学的“绿色化”具有重要的意义，对其他功能材料的构筑也具有重要的参考价值和指导意义。
근거배호정연생물분자결구여형태적불동，분류종술료배호정연생물（이β-배호정연생물위주）적형태급기구축책략연구진전，포괄단취대배호정연생물、쌍취대배호정연생물、다취대배호정연생물、이취체배호정연생물、다취체배호정연생물화배호정취합물（포괄고재화배호정）。지출배호정연생물적구축시기우배호정구축각충공능재료적기출여관건，시배호정모체응용적진일보탁전。기우배호정구축각충초분자방매，불부가이충분발휘배호정결구상적선천우세，야가이실현유궤합성반응종유궤상도수상적순리과도，병제고반응적선택성，대유궤합성화학적“록색화”구유중요적의의，대기타공능재료적구축야구유중요적삼고개치화지도의의。
The molecular morphology of cyclodextrin derivatives and their construction strategy (mainly theβ-cyclodextrin derivatives) were reviewed comprehensively according to the difference in molecular structure and morphology,including mono-substituted cyclodextrin derivatives, bis-substituted cyclodextrin derivatives,multi-substituted cyclodextrin derivatives,dimer cyclodextrin derivatives,multimer cyclodextrin derivatives and cyclodextrin polymers (including immobilized cyclodextrins). It was pointed out that the construction of cyclodextrin derivatives was the foundation and key step in the building of various functional materials,could be further expanded in the application of parent cyclodextrin. To construct various supramolecular artificial enzymes based on cyclodextrin,not only can make full use of the inherent advantages of cyclodextrin structure,but also can realize the smooth transition of organic synthesis reactions from organic phase to aqueous phase with enhanced selectivity,which have great significance for the greenization of organic synthetic chemistry,important reference value and instructive significance for the construction of other functional materials.