辽宁石油化工大学学报
遼寧石油化工大學學報
료녕석유화공대학학보
JOURNAL OF LIAONING UNIVERSITY OF PETROLEUM & CHEMICAL TECHNOLOGY
2015年
1期
20-23
,共4页
申云生%马海燕%温博%宋燊%廉玮
申雲生%馬海燕%溫博%宋燊%廉瑋
신운생%마해연%온박%송신%렴위
页岩油%萃取精制%络合精制%催化裂化%加工工艺
頁巖油%萃取精製%絡閤精製%催化裂化%加工工藝
혈암유%췌취정제%락합정제%최화열화%가공공예
Shale oil%Extraction refining%Complexing refining%Catalytic cracking%Processing technology
对抚顺页岩油萃取精制、调和、络合精制和催化裂化加工方案进行了研究。结果表明,抽出油黏性小、塑性大、感温性好,可调和多种牌号的沥青;所剩轻组分可用于非烃化合物的分离。采用酸性络合剂对抽余油进行络合精制,在剂油质量比为2∶3时,其总氮质量分数可控制在3000μg/g以内,碱性氮质量分数可控制在100μg/g以内;精制后抽余油催化裂化性能良好,与石油中的蜡油组分性能相近。
對撫順頁巖油萃取精製、調和、絡閤精製和催化裂化加工方案進行瞭研究。結果錶明,抽齣油黏性小、塑性大、感溫性好,可調和多種牌號的瀝青;所剩輕組分可用于非烴化閤物的分離。採用痠性絡閤劑對抽餘油進行絡閤精製,在劑油質量比為2∶3時,其總氮質量分數可控製在3000μg/g以內,堿性氮質量分數可控製在100μg/g以內;精製後抽餘油催化裂化性能良好,與石油中的蠟油組分性能相近。
대무순혈암유췌취정제、조화、락합정제화최화열화가공방안진행료연구。결과표명,추출유점성소、소성대、감온성호,가조화다충패호적력청;소잉경조분가용우비경화합물적분리。채용산성락합제대추여유진행락합정제,재제유질량비위2∶3시,기총담질량분수가공제재3000μg/g이내,감성담질량분수가공제재100μg/g이내;정제후추여유최화열화성능량호,여석유중적사유조분성능상근。
Through extraction refining,harmonization,complexing refining and catalytic cracking of Fushun shale oil,which provided references for processing and utilization of Fushun shale oil,it showed that the extract oil could harmonize various grades of asphalt,due to small viscosity,large ductility and better temperature serviceability.At the same time,light components left could be used for separation of non-hydrocarbon compounds.Using acidic as complexing agent with the ratio of solvent to oil 2∶3,the total nitrogen content of the raffinate oil was within in 3 000 μg/g and alkali nitrogen compounds of the raffinate oil was less than 100 μg/g .After complexing refining,the catalytic cracking performance of raffinate oil was good, which was similar with the paraffinoil.