CAJ | 학술논문

以3,3?-二氯联苯胺为模板分子，甲基丙烯酸为功能单体，偶氮二异丁腈为引发剂，乙二醇二甲基丙烯酸酯作为交联剂，1-丁基-3-甲基咪唑六氟磷酸盐离子液体为致孔剂，乙腈和氯仿混合溶液为溶剂，合成了3,3?-二氯联苯胺分子印迹整体柱。考察了3,3?-二氯联苯胺分子印迹整体聚合物的结合性质及其在3,3?-二氯联苯胺分子聚合物上的选择性分离富集特性。得到的分子印迹聚合物整体柱，对模板分子具有特异的识别能力，在所选择的色谱条件下，3,3?-二氯联苯胺与类似物可以得到较好的分离。
이3,3?-이록련분알위모판분자，갑기병희산위공능단체，우담이이정정위인발제，을이순이갑기병희산지작위교련제，1-정기-3-갑기미서륙불린산염리자액체위치공제，을정화록방혼합용액위용제，합성료3,3?-이록련분알분자인적정체주。고찰료3,3?-이록련분알분자인적정체취합물적결합성질급기재3,3?-이록련분알분자취합물상적선택성분리부집특성。득도적분자인적취합물정체주，대모판분자구유특이적식별능력，재소선택적색보조건하，3,3?-이록련분알여유사물가이득도교호적분리。
Using 3,3’-dichlorobenzidine as the template, methacrylic acid (MAA) as the functional monomer, azobisisobutyronitrile (AIBN) as a initiator, ethylene glycol dimethacrylate (EGDMA) as the cross-linker, BMIMPF6 as the porogent, and the mixture of acetonitrile and chloroform as the solvent, a 3,3’-dichlorobenzidine imprinted monolithic column was prepared by in situ molecular imprinting technique, and its binding properties and selectivity were investigated. The 3,3’-dichlorobenzidine molecularly imprinted monolithic polymer has specific recognition ability for 3,3’-dichlorobenzidine.3,3?-dichlorobenzidine and its structural analogues were separated under selected conditions.