CAJ | 학술논문

目的综合利用我国丰富的非水溶性钾矿，以缓解我国钾肥市场“供－需”矛盾．方法通过水浸提和盆栽试验，比较了活化剂QN对富钾页岩和钾长石的活化效果，并通过X衍射分析活化剂QN对富钾页岩和钾长石的作用机理．结果和结论水浸提试验结果表明，在QN比例0.1％～10.0％范围内，富钾页岩、钾长石的活化效果不同，随QN比例的增加，活化页岩的水溶性钾释放量先增加后下降，1.0％QN活化页岩的水溶性钾累积量最高；活化钾长石的水溶性钾含量则随QN比例的增加而增加，QN比例为10.0％时的水溶性钾累积量最高．盆栽结果表明，活化页岩的玉米生物量显著高于富钾页岩，而与氯化钾的生物量相当；活化钾长石处理的玉米生物量与钾长石处理差异不显著，且显著低于氯化钾活化页岩处理．X衍射结果分析表明，QN活化富钾页岩和钾长石的作用机理是Na＋与K＋间的交换反应，活化页岩中新增的钠盐有K0.96 Na0.04 AlSi3 O8、Na4 Al2 Si6 O17·2H2 O和Na6 PbO4，活化钾长石中新增的钠盐为Na3 Mn（ PO4）（ CO3）．
목적종합이용아국봉부적비수용성갑광，이완해아국갑비시장“공－수”모순．방법통과수침제화분재시험，비교료활화제QN대부갑혈암화갑장석적활화효과，병통과X연사분석활화제QN대부갑혈암화갑장석적작용궤리．결과화결론수침제시험결과표명，재QN비례0.1％～10.0％범위내，부갑혈암、갑장석적활화효과불동，수QN비례적증가，활화혈암적수용성갑석방량선증가후하강，1.0％QN활화혈암적수용성갑루적량최고；활화갑장석적수용성갑함량칙수QN비례적증가이증가，QN비례위10.0％시적수용성갑루적량최고．분재결과표명，활화혈암적옥미생물량현저고우부갑혈암，이여록화갑적생물량상당；활화갑장석처리적옥미생물량여갑장석처리차이불현저，차현저저우록화갑활화혈암처리．X연사결과분석표명，QN활화부갑혈암화갑장석적작용궤리시Na＋여K＋간적교환반응，활화혈암중신증적납염유K0.96 Na0.04 AlSi3 O8、Na4 Al2 Si6 O17·2H2 O화Na6 PbO4，활화갑장석중신증적납염위Na3 Mn（ PO4）（ CO3）．
Objective] Comprehensive utilization of water-insoluble potassium resources is helpful to re-lieve the contradiction between supply and demand of potash market .[Method] The activated effects and fertilizer effects were studied by water extraction experiment and pot trial .The mechanism of activation was discussed by X-ray diffraction (XRD).[Result and conclusion] The results of water extraction ex-periment indicated that , within the QN ratio of 0.1%-10.0%, potassium-rich shale and potassium feld-spar had different activated effects .With the increase of QN ratio , the water-soluble K extraction from potassium-rich shale increased and then decreased , and the activated ratio of 1.0%was the best .For po-tassium feldspar , the water-soluble K accumulative amount increased as the ratio of QN increased , and when the QN ratio was 10.0%, the accumulation of water-soluble K was the highest .The pot trail results showed that the pot biomass of activated K-shale was 49.42%higher than that of K-shale, reaching the potassium chloride level .For activated K-feldspar , the corn biomass was not significantly different from K-feldspar , which was lower than that of K-chloride and activated K-shale .The results of XRD analysis indicated that , the mechanism of QN activated potassium-rich shale and potassium feldspar was an ion ex-change reaction between Na + and K+.Some new sodium minerals can be found in activated K-shale andactivated K-feldspar.In activated K-shale, the new sodium minerals include K0.96 Na0.04 AlSi3 O8 ,Na4 Al2 Si6 O17·2H2 O and Na6 PbO4 , but it is Na3 Mn(PO4 )(CO3 ) in activated K-feldspar.