石油炼制与化工
石油煉製與化工
석유련제여화공
PETROLEUM PROCESSING AND PETROCHEMICALS
2015年
2期
64-70
,共7页
王帅%赵瑞玉%杨朝合%刘晨光
王帥%趙瑞玉%楊朝閤%劉晨光
왕수%조서옥%양조합%류신광
FDU-1 2%扩散%重质油%吸附扩散法%孔径
FDU-1 2%擴散%重質油%吸附擴散法%孔徑
FDU-1 2%확산%중질유%흡부확산법%공경
FDU-1 2%diffusion%heavy oil%adsorption and diffusion method%p ore size
采用F127为模板剂、正硅酸四乙酯为硅源,经水热法合成了 FDU-12介孔分子筛,将其作为模型孔道催化剂用于沥青质的扩散研究。通过N2吸附-脱附、XRD、TEM、SEM等对 FDU-12进行表征。结果表明:升高晶化温度能够增大催化剂孔道的入口孔径,而笼孔径不变;降低组装温度能够增大分子筛的笼孔径,而入口孔径不变。运用吸附扩散法测定了沥青质在模型孔道催化剂中的有效扩散系数。结果表明:增加模型催化剂的入口孔径和笼孔径在一定范围内能够提高有效扩散系数,但是孔径过大会导致载体的比表面积下降,使有效扩散系数降低。
採用F127為模闆劑、正硅痠四乙酯為硅源,經水熱法閤成瞭 FDU-12介孔分子篩,將其作為模型孔道催化劑用于瀝青質的擴散研究。通過N2吸附-脫附、XRD、TEM、SEM等對 FDU-12進行錶徵。結果錶明:升高晶化溫度能夠增大催化劑孔道的入口孔徑,而籠孔徑不變;降低組裝溫度能夠增大分子篩的籠孔徑,而入口孔徑不變。運用吸附擴散法測定瞭瀝青質在模型孔道催化劑中的有效擴散繫數。結果錶明:增加模型催化劑的入口孔徑和籠孔徑在一定範圍內能夠提高有效擴散繫數,但是孔徑過大會導緻載體的比錶麵積下降,使有效擴散繫數降低。
채용F127위모판제、정규산사을지위규원,경수열법합성료 FDU-12개공분자사,장기작위모형공도최화제용우력청질적확산연구。통과N2흡부-탈부、XRD、TEM、SEM등대 FDU-12진행표정。결과표명:승고정화온도능구증대최화제공도적입구공경,이롱공경불변;강저조장온도능구증대분자사적롱공경,이입구공경불변。운용흡부확산법측정료력청질재모형공도최화제중적유효확산계수。결과표명:증가모형최화제적입구공경화롱공경재일정범위내능구제고유효확산계수,단시공경과대회도치재체적비표면적하강,사유효확산계수강저。
Using F127 as template agent,tetraethyl orthosilicate as silicon source,a series of meso-poreous silica FDU-1 2 s as model catalysts were synthesized under different conditions for investigation of diffusivity of asphaltene.The catalysts were characterized by BET,XRD,TEM,SEM techniques.The influence of assemble temperature and crystallization temperature on the pore size of the materials was investigated.The diffusivities of asphaltene in the catalysts with different pore size were studied.The results show that rising the crystallization temperature can only enlarge the pore mouth size of FDU-1 2 molecular sieves without the increase of cage diameter,while lowering the assemble tempera-ture has a opposite effect.Increase of entrance pore size and cage size of FDU-1 2 enhances the effective diffusivity;however,the decrease of specific surface due to excessive increase of pore size can reduce ef-fective diffusivity.