CAJ | 학술논문

采用氯磺酸磺化法合成了一种含有磺酸基和羧基的新型络合剂磺化戊二酸（SG），用 SG与乙二胺四乙酸、柠檬酸、FeCl3配制出一种三元络合铁脱硫体系。在连续脱硫装置中考察脱硫液与硫化氢气体体积比、装置运行时间、填料高度等脱硫工艺条件对复配脱硫体系脱硫效率的影响，在再生装置中考察空气流量、再生时间、再生温度等再生工艺条件对复配脱硫体系再生率的影响。结果表明：在脱硫液与含硫化氢原料气体积比为0.134、填料高度为0.4 m、脱硫温度为40℃、初始 pH为8.0的条件下，原料气中的 H2 S质量浓度可由227.679 g？m3降到0.011 g？m3，脱除率达99.99％；在空气流量为125 L？h、再生时间为30 min、温度为30℃、初始 pH为8.0的条件下，脱硫剂的再生率达93.24％。
채용록광산광화법합성료일충함유광산기화최기적신형락합제광화무이산（SG），용 SG여을이알사을산、저몽산、FeCl3배제출일충삼원락합철탈류체계。재련속탈류장치중고찰탈류액여류화경기체체적비、장치운행시간、전료고도등탈류공예조건대복배탈류체계탈류효솔적영향，재재생장치중고찰공기류량、재생시간、재생온도등재생공예조건대복배탈류체계재생솔적영향。결과표명：재탈류액여함류화경원료기체적비위0.134、전료고도위0.4 m、탈류온도위40℃、초시 pH위8.0적조건하，원료기중적 H2 S질량농도가유227.679 g？m3강도0.011 g？m3，탈제솔체99.99％；재공기류량위125 L？h、재생시간위30 min、온도위30℃、초시 pH위8.0적조건하，탈류제적재생솔체93.24％。
A new complexing agent SG containing sulfonic group and carboxylic group is synthesized using chlorosulfonic acid and glutaric acid.The ternary complex iron desulfurization system is prepared with SG,EDTA,citric acid and Fe3+.In a continuous desulfurization device,the effect of liquid to feed gas ratio,running time and filler height on the desulfurization efficiency of the ternary system is stud-ied.The effect of air flow rate,regeneration time and temperature on the regeneration for the ternary system is also investigated.The optimum desulfurization conditions are approached as follows:the liq-uid?feed gas ratio of 0.134,the packing height of 0.4 m,the temperature of 40 ℃ and pH of 8.0.In this case,the H2S content of the feed gas is reduced from 227.679 g?m3 to 0.011 g?m3,the removal rate is up to 99.99%.The regeneration rate is up to 93.24% at the optimum regeneration conditions:the air flow of 125 L?h,the regeneration time of 30 min,the regeneration temperature of 30 ℃ and pH of 8.0.