稀土学报（英文版）
稀土學報（英文版）
희토학보（영문판）
JOURNAL OF RARE EARTHS
2015年
2期
135-139
,共5页
茹晶晶%秦小焕%颜桂炀%陈建中
茹晶晶%秦小煥%顏桂煬%陳建中
여정정%진소환%안계양%진건중
tungstate%rare earth%luminescence%LED
Ca3R2–xWO9:xEu3+(R=Y, Gd) red-emitting phosphors were prepared by solid state reactions. These samples were charac-terized by differential scanning calorimetry and thermogravimetry analysis (DSC-TGA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), photoluminescence (PL) and field emission scanning electron microscopy (FE-SEM) analyses. The optimum sintering temperature for these phosphors was 1100 oC, and the optimum sintering time was 2 h. The optimum doped con-centration of Eu3+in Ca3Y2–xWO9:xEu3+and Ca3Gd2–xWO9:xEu3+were x=1.5 and x=1.1, respectively. These phosphors could be ex-cited by near-UV light of 394 nm and blue light of 465 nm, and showed strong red emission line at 612 nm (5D0→7F2), which indi-cated that Ca3R2–xWO9:xEu3+(R=Y, Gd) were promising red candidates for white LED.
