工业水处理
工業水處理
공업수처리
INDUSTRIAL WATER TREATMENT
2015年
1期
80-83
,共4页
董社英%张黎黎%钮丽%黄廷林
董社英%張黎黎%鈕麗%黃廷林
동사영%장려려%뉴려%황정림
三元共聚物%微波合成%性能%阻垢机理%衣康酸
三元共聚物%微波閤成%性能%阻垢機理%衣康痠
삼원공취물%미파합성%성능%조구궤리%의강산
terpolymer%microwave synthesis%capacity%scale inhibiting mechanism%itaconic acid
以衣康酸、丙烯磺酸钠、马来酸为单体,采用微波辐射法合成了IA-MA-SAS三元共聚物。分别利用热重、透光率测试、静态阻垢法和电导法测定分析了其热稳定性、分散氧化铁性能和阻垢性能。通过扫描电镜和X衍射观察分析沉积物形貌,探讨了阻垢机理。结果表明:IA-MA-SAS具有良好的阻垢性能、热稳定性和分散氧化铁性能;其阻垢机理主要有晶格畸变、螯合和分散作用;与聚天冬氨酸有很好的协同效应,阻垢率可达95%以上。
以衣康痠、丙烯磺痠鈉、馬來痠為單體,採用微波輻射法閤成瞭IA-MA-SAS三元共聚物。分彆利用熱重、透光率測試、靜態阻垢法和電導法測定分析瞭其熱穩定性、分散氧化鐵性能和阻垢性能。通過掃描電鏡和X衍射觀察分析沉積物形貌,探討瞭阻垢機理。結果錶明:IA-MA-SAS具有良好的阻垢性能、熱穩定性和分散氧化鐵性能;其阻垢機理主要有晶格畸變、螯閤和分散作用;與聚天鼕氨痠有很好的協同效應,阻垢率可達95%以上。
이의강산、병희광산납、마래산위단체,채용미파복사법합성료IA-MA-SAS삼원공취물。분별이용열중、투광솔측시、정태조구법화전도법측정분석료기열은정성、분산양화철성능화조구성능。통과소묘전경화X연사관찰분석침적물형모,탐토료조구궤리。결과표명:IA-MA-SAS구유량호적조구성능、열은정성화분산양화철성능;기조구궤리주요유정격기변、오합화분산작용;여취천동안산유흔호적협동효응,조구솔가체95%이상。
A new kind of green scale inhibitor,IA-MA-SAS terpolymer,has been synthesized with itaconic acid, acrylic sodium sulfonate and maleic anhydride as monomers by microwave radiation method. Its thermal stability , iron oxide distributing capacity,and scale inhibiting capacity for calcium carbonate (CaCO3) scale have been mea-sured and analyzed by thermal gravimetry,transmission tests,static scale inhibition and electric conduction method. Furthermore,the morphology and crystal structure of sediments are analyzed by scanning electron microscope and X-ray diffraction,and the scale inhibiting mechanisms discussed. The results show that IA-MA-SAS has good scale inhibiting capacity for CaCO3 scale,good thermal stability and good dispersion capacity for Fe2O3. And its scale in-hibition mechanism is related to lattice distortion effect ,chelation and dispersive effect. In addition ,it has good syn-ergistic effect with polyaspartic acid. Its scale inhibiting rate can be higher than 95%.