火炸药学报
火炸藥學報
화작약학보
CHINESE JOURNAL OF EXPLOSIVES & PROPELLANTS
2014年
6期
83-86
,共4页
杨建兴%舒安民%马方生%贾永杰%辛凯迪
楊建興%舒安民%馬方生%賈永傑%辛凱迪
양건흥%서안민%마방생%가영걸%신개적
物理化学%高能硝胺发射药%GAP%抗冲强度%燃烧性能
物理化學%高能硝胺髮射藥%GAP%抗遲彊度%燃燒性能
물이화학%고능초알발사약%GAP%항충강도%연소성능
physical chemistry%high energy nitramine gun propellant%GAP%impact strength%combustion performance
为改进高能硝胺发射药的力学性能,制备了含缩水甘油叠氮聚醚(GAP)的单孔管状硝胺发射药,用材料试验机测试其冲击和压缩性能,通过扫描电镜观察其内部形貌,用密闭爆发器分析了其燃烧性能。结果表明,GAP可改善高能硝胺发射药的力学性能,加入质量分数1.5%GAP 时,高能硝胺发射药的低温抗冲强度由基础配方的4.51 kJ/m2提高到5.58 kJ/m2,GAP的加入使固体填料与黏结剂体系界面间的黏接强度提高,脱湿现象减少;随着GAP含量的增加,管状发射药的压强指数(n)相比基础配方增加,爆温(Tv )及火药力(f)逐渐降低,GAP 质量分数为3.5%时,与基础配方相比,f、Tv 分别降低1.41%、3.69%,n增加0.51%。
為改進高能硝胺髮射藥的力學性能,製備瞭含縮水甘油疊氮聚醚(GAP)的單孔管狀硝胺髮射藥,用材料試驗機測試其遲擊和壓縮性能,通過掃描電鏡觀察其內部形貌,用密閉爆髮器分析瞭其燃燒性能。結果錶明,GAP可改善高能硝胺髮射藥的力學性能,加入質量分數1.5%GAP 時,高能硝胺髮射藥的低溫抗遲彊度由基礎配方的4.51 kJ/m2提高到5.58 kJ/m2,GAP的加入使固體填料與黏結劑體繫界麵間的黏接彊度提高,脫濕現象減少;隨著GAP含量的增加,管狀髮射藥的壓彊指數(n)相比基礎配方增加,爆溫(Tv )及火藥力(f)逐漸降低,GAP 質量分數為3.5%時,與基礎配方相比,f、Tv 分彆降低1.41%、3.69%,n增加0.51%。
위개진고능초알발사약적역학성능,제비료함축수감유첩담취미(GAP)적단공관상초알발사약,용재료시험궤측시기충격화압축성능,통과소묘전경관찰기내부형모,용밀폐폭발기분석료기연소성능。결과표명,GAP가개선고능초알발사약적역학성능,가입질량분수1.5%GAP 시,고능초알발사약적저온항충강도유기출배방적4.51 kJ/m2제고도5.58 kJ/m2,GAP적가입사고체전료여점결제체계계면간적점접강도제고,탈습현상감소;수착GAP함량적증가,관상발사약적압강지수(n)상비기출배방증가,폭온(Tv )급화약력(f)축점강저,GAP 질량분수위3.5%시,여기출배방상비,f、Tv 분별강저1.41%、3.69%,n증가0.51%。
To improve the mechanical performance of high energy nitramine gun propellant,the single perforation cylinder propellant containing GAP was prepared.The impact and compression performance of the gun propellant were studied by a material testing machine.The internal morphology of the gun propellant was observed by SEM and the combustion performance was analyzed by a closed bomb test.The results show that the mechanical perform-ance of the high energy nitramine gun propellant can be improved by adding GAP.When the mass fraction of GAP is 1 .5%,the impact strength of high energy nitramine gun propellant at low temperature can be increased from 4 .5 1 kJ/m2 of basic formula to 5.58 kJ/m2 .Adding GAP makes the bonding strength between the interfaces of solid filling and binder system enhance and the dehumidifying phenomenon reduce.With increasing the mass fraction of GAP,in comparison with the basic formula,the burning rate pressure exponent (n)of the perforation cylinder propellant increases,and the explosion temperature (Tv )and impetus (f)of gun propellant decrease gradually.When the mass fraction of GAP is 3.5%,thef,Tv decrease by 1.41%,3.69%,andnincreases by 0.51%,respectively.