CAJ | 학술논문

利用电子关联效应和相对论效应的Hartree-Fock(HFR)自洽场方法(SCF)，计算了Kr原子在基态4p6和激发态1s-15s，2s-15s，2p-15s，3s-15s，3p-15s，3d-15s，4s-15s，4p-15s情况下的各壳层电子的轨道半径、有效量子数、束缚能及径向波函数，系统地研究了内壳层电子激发导致的电子波函数的弛豫现象。结果表明，对于同一电子轨道，越是内壳层电子激发，驰豫效应的影响越明显；对于同一激发态，驰豫效应对较外壳层电子的影响要大于对较内壳层电子的影响。
이용전자관련효응화상대론효응적Hartree-Fock(HFR)자흡장방법(SCF)，계산료Kr원자재기태4p6화격발태1s-15s，2s-15s，2p-15s，3s-15s，3p-15s，3d-15s，4s-15s，4p-15s정황하적각각층전자적궤도반경、유효양자수、속박능급경향파함수，계통지연구료내각층전자격발도치적전자파함수적이예현상。결과표명，대우동일전자궤도，월시내각층전자격발，치예효응적영향월명현；대우동일격발태，치예효응대교외각층전자적영향요대우대교내각층전자적영향。
Self-consistent-field calculations of the orbital radii and binding energy and radial wave function of the subshell electrons in the ground state 4p6 and eight excited state 1s-15s,2s-15s,2p-15s,3s-15s,3p-15s,3d-15s,4s-15s, and 4p-15s in Krypton have been made by using relativistic Hartree-Fork(HFR). The relaxation effects induced by excitation (or ionization) of inner subshell electrons and their influences on the electronic wave functions have been systematically studied. The experiment and analysis shows that that the more inner-shell electron is excited, the effects of relaxation is more obvious. In the same excitation state, the influence of the relaxation effects on the outer electron is greater than the inner-shell electrons.