CAJ | 학술논문

为从分子尺度优化C－S－H微结构提供理论依据，采用模拟大体积混凝土内部变温历程的养护制度，运用29 Si魔角旋转核磁共振（29 Si MAS NMR）结合去卷积技术，研究了变温条件下Ba（OH）2掺量为1.0％时对水泥浆体C－S－H微结构的影响规律。结果表明：在变温条件下掺加Ba（OH）2提高了水泥浆体中硅酸盐矿物水化程度，尤其在水化早期（3 d）时硅酸盐矿物水化程度增幅较大，进而使C－S－H结构中硅氧四面体二聚体数量增加，导致其C－S－H平均分子链长（MCL）显著低于纯水泥浆体，避免了纯水泥浆体在降温阶段出现C－S－H的MCL降低的现象。同时，掺加Ba（OH）2进一步降低了水泥浆体在变温过程下C－S－H中Al3＋取代Si4＋的程度。
위종분자척도우화C－S－H미결구제공이론의거，채용모의대체적혼응토내부변온역정적양호제도，운용29 Si마각선전핵자공진（29 Si MAS NMR）결합거권적기술，연구료변온조건하Ba（OH）2참량위1.0％시대수니장체C－S－H미결구적영향규률。결과표명：재변온조건하참가Ba（OH）2제고료수니장체중규산염광물수화정도，우기재수화조기（3 d）시규산염광물수화정도증폭교대，진이사C－S－H결구중규양사면체이취체수량증가，도치기C－S－H평균분자련장（MCL）현저저우순수니장체，피면료순수니장체재강온계단출현C－S－H적MCL강저적현상。동시，참가Ba（OH）2진일보강저료수니장체재변온과정하C－S－H중Al3＋취대Si4＋적정도。
In order to provide the theoretical basis for optimizing the microstructure of C -S -H at molecular scale,by simulating the variable temperature process in the interior of mass concrete and using the 29 Si Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR)combined with deconvolution technique,effect of 1.0% Ba(OH)2 on C-S-H microstructure in Portland cement pastes at variable temperature regime was in-vestigated.The results show that the hydration of silicate minerals in cement pastes is improved by mixing the Ba(OH)2 at variable temperature regime,especially at the early stage hydration(3 d).The amount of silicate tetrahedra dimers is increased,leading to the mean chain length (MCL)of C -S -H in cement pastes with Ba(OH)2 lower than that in pure cement pastes,avoiding the phenomenon of C-S-H MCL reduction in pure cement pastes at the cooling stage.Meanwhile,the degree of Al3+substituting for Si4+is further decreased by adding to Ba(OH)2 in cement pastes at variable temperature regime.