催化学报
催化學報
최화학보
CHINESE JOURNAL OF CATALYSIS
2015年
2期
221-228
,共8页
胡晓静%石玉坤%朱宝林%张守民%黄唯平
鬍曉靜%石玉坤%硃寶林%張守民%黃唯平
호효정%석옥곤%주보림%장수민%황유평
二氧化钛纳米管%钯%活性物种%光降解%甲基橙
二氧化鈦納米管%鈀%活性物種%光降解%甲基橙
이양화태납미관%파%활성물충%광강해%갑기등
Titania nanotube%Palladium%Active species%Photodegradation%Methyl orange
采用光沉积法制备了光稳定二氧化钛纳米管负载钯催化剂.通过X射线衍射、紫外-可见漫反射光谱、透射电子显微镜(TEM)、氮气吸附-脱附、X射线光电子能谱(XPS)、光致发光光谱和光电流等表征手段研究了催化剂的结构和性质. TEM表明二氧化钛纳米管经光照后仍然保持良好的管状结构; XPS结果表明大部分Pd以零价形式存在.以甲基橙溶液作为模拟废液研究了催化剂在紫外光及模拟日光条件下的光催化活性.当Pd的负载量为0.3 wt%时,催化剂的光催化活性最高并且优于P25的光催化活性.另外,通过在光降解过程中加入不同的捕获剂研究了不同氧化活性组分的作用.结果表明,光生空穴(hvb+)在光催化降解过程中起主要作用.
採用光沉積法製備瞭光穩定二氧化鈦納米管負載鈀催化劑.通過X射線衍射、紫外-可見漫反射光譜、透射電子顯微鏡(TEM)、氮氣吸附-脫附、X射線光電子能譜(XPS)、光緻髮光光譜和光電流等錶徵手段研究瞭催化劑的結構和性質. TEM錶明二氧化鈦納米管經光照後仍然保持良好的管狀結構; XPS結果錶明大部分Pd以零價形式存在.以甲基橙溶液作為模擬廢液研究瞭催化劑在紫外光及模擬日光條件下的光催化活性.噹Pd的負載量為0.3 wt%時,催化劑的光催化活性最高併且優于P25的光催化活性.另外,通過在光降解過程中加入不同的捕穫劑研究瞭不同氧化活性組分的作用.結果錶明,光生空穴(hvb+)在光催化降解過程中起主要作用.
채용광침적법제비료광은정이양화태납미관부재파최화제.통과X사선연사、자외-가견만반사광보、투사전자현미경(TEM)、담기흡부-탈부、X사선광전자능보(XPS)、광치발광광보화광전류등표정수단연구료최화제적결구화성질. TEM표명이양화태납미관경광조후잉연보지량호적관상결구; XPS결과표명대부분Pd이령개형식존재.이갑기등용액작위모의폐액연구료최화제재자외광급모의일광조건하적광최화활성.당Pd적부재량위0.3 wt%시,최화제적광최화활성최고병차우우P25적광최화활성.령외,통과재광강해과정중가입불동적포획제연구료불동양화활성조분적작용.결과표명,광생공혈(hvb+)재광최화강해과정중기주요작용.
Highly photostable palladium‐loaded TiO2 nanotubes (Pd/TNTs) were prepared by a simple pho‐to‐decomposition method and characterized by inductively coupled plasma, X‐ray diffraction, UV‐visible light diffuse reflectance spectroscopy, transmission electron microscopy (TEM), X‐ray photoelectron spectroscopy (XPS), photoluminescence spectroscopy, N2 adsorption‐desorption, and photocurrent measurement. TEM images showed that the samples had a tubular structure. XPS results revealed that most of the palladium was present as Pd0. The photocatalytic performance was evaluated by monitoring the catalytic activity for the degradation of methyl orange solution under both UV and simulated sunlight irradiation. Pd/TNTs with 0.3 wt% Pd displayed higher activity than P25. The active species in the photocatalytic process were investigated by using different types of active species scavengers. hvb+was the major reactive species in the photodegradation over the Pd/TNTs.