广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2015年
1期
127-128,131
,共3页
HNO3%H2 O2%生物炭%湿式氧化%苯酚
HNO3%H2 O2%生物炭%濕式氧化%苯酚
HNO3%H2 O2%생물탄%습식양화%분분
HNO3%H2 O2%biochar%wet peroxide oxidation%phenol
采用经H2 O2和Ar/H2 O改性处理的生物炭处理高浓度含苯酚废水，以N2低温物理吸附和红外光谱技术对催化剂结构与性能之间的关系进行了研究。结果发现Ar/H2 O混合气体处理生物炭材料，可以降低材料表面酸性位的数目，显著增加材料表面的电子密度，可以有效促进H2 O2得电子生成羟基自由基，进而提高了苯酚的氧化分解速率。
採用經H2 O2和Ar/H2 O改性處理的生物炭處理高濃度含苯酚廢水，以N2低溫物理吸附和紅外光譜技術對催化劑結構與性能之間的關繫進行瞭研究。結果髮現Ar/H2 O混閤氣體處理生物炭材料，可以降低材料錶麵痠性位的數目，顯著增加材料錶麵的電子密度，可以有效促進H2 O2得電子生成羥基自由基，進而提高瞭苯酚的氧化分解速率。
채용경H2 O2화Ar/H2 O개성처리적생물탄처리고농도함분분폐수，이N2저온물리흡부화홍외광보기술대최화제결구여성능지간적관계진행료연구。결과발현Ar/H2 O혼합기체처리생물탄재료，가이강저재료표면산성위적수목，현저증가재료표면적전자밀도，가이유효촉진H2 O2득전자생성간기자유기，진이제고료분분적양화분해속솔。
In this paper, we treat of waste-water which contained high concentration of phenol by using H2 O2 and Ar/H2 O modified biochar. Cryogenic physical adsorption of N2 and infrared spectroscopy were used as studied the structure and properties of the catalyst. The results showed that the acid sites numbers of surface can be reduced by handling biological carbon materials which used the mixed gas of Ar/H2 O, so that the surface of the electron density of the material increases significantly and the process of H2 O2 obtained electronic to generate hydroxyl radicals was effectively promoted. Thereby it was increased the rate of oxidative decomposition of phenol.
