CAJ | 학술논문

通过测定洋山深水港区海域2010-2013年6个航次秋、冬季沉积物中重金属含量，分析其时空差异，结果表明该海域沉积物重金属总体含量较低，空间分布较为均匀，Hg、Zn、Pb、Cd含量秋季明显高于冬季，As、Cu含量的季节性波动较小。用因子分析法研究该海域重金属来源，发现陆源工业、船舶航运排污以及有机质降解是研究海域Pb、Cd、Zn的主要来源；农业污染、码头货物装卸残留及建筑垃圾支配着Cu、As、Hg的来源。基于平均沉积物质量基准系数法(SQG-Q)的生态风险评价结果表明研究海域沉积物中重金属均存在中、低度的生态风险，秋季的生态风险高于冬季，Hg和Cu是主要生态风险因子；地累积指数法评价结果显示研究海域基本不受Hg、As、Zn、Pb的污染；Cd、Cu以轻度污染为主，部分站位属于偏中度污染，6种重金属污染程度依次为：Cd跃Cu跃Pb跃Zn跃Hg跃As。因子综合得分评价表明，重金属污染相对严重的站位依次为5号、4号及3号站位。但总体看来，洋山深水港区附近海域沉积物中重金属污染状况属于轻度污染。
통과측정양산심수항구해역2010-2013년6개항차추、동계침적물중중금속함량，분석기시공차이，결과표명해해역침적물중금속총체함량교저，공간분포교위균균，Hg、Zn、Pb、Cd함량추계명현고우동계，As、Cu함량적계절성파동교소。용인자분석법연구해해역중금속래원，발현륙원공업、선박항운배오이급유궤질강해시연구해역Pb、Cd、Zn적주요래원；농업오염、마두화물장사잔류급건축랄급지배착Cu、As、Hg적래원。기우평균침적물질량기준계수법(SQG-Q)적생태풍험평개결과표명연구해역침적물중중금속균존재중、저도적생태풍험，추계적생태풍험고우동계，Hg화Cu시주요생태풍험인자；지루적지수법평개결과현시연구해역기본불수Hg、As、Zn、Pb적오염；Cd、Cu이경도오염위주，부분참위속우편중도오염，6충중금속오염정도의차위：Cd약Cu약Pb약Zn약Hg약As。인자종합득분평개표명，중금속오염상대엄중적참위의차위5호、4호급3호참위。단총체간래，양산심수항구부근해역침적물중중금속오염상황속우경도오염。
Temporal and spatial variations of concentrations for heavy metals including mercury (Hg), zinc (Zn), lead (Pb), arsenic (As), copper (Cu), and cadmium (Cd) in the sediments of Yangshan Deepwater Harbor were determined based on 6 cruises in autumns and winters, respectively, from 2010 to 2013.The results demonstrated that the overall concentrations of heavy metals were low and distributing in uniform patterns. Concentrations of Hg, Zn, Pb, and Cd in autumns were significantly higher than that in winter, with smooth fluctuations for As and Cu in terms of seasonal variations. Results of factor analysis showed that Pb, Cd, and Zn derived from inland industrial and shipping discharges as well as the degradation of organic pollutants in marine environment. While agricultural pollutions, cargo shifting and construction debris from reclamation projects contributed to the source of Cu, As, and Hg. Ecological risk assessment by Mean Sediment Quality Guideline Quotient (SQG-Q) revealed that the degree for eco-risk of the sediments were low-and-moderate in autumns, higher than that in winters. Hg and Cu were the dominant eco-risk factors. The results of Index of geoaccumulation (Igeo) showed that the whole sites of the sea area were barely influenced by Hg, As, Zn, and Pb, the extents of Cd and Cu contaminations were in low grade. Contamination degree of all the six heavy metals could be ranked as the following: Cd>Pb>Zn>Hg>As. According to the results of integrated score of factor analysis, heavy metal contamination in the study area were in low grade, Station 5, 4 and 3 showed relatively heavy contamination compared with other stations.