表面技术
錶麵技術
표면기술
SURFACE TECHNOLOGY
2015年
1期
15-23,40
,共10页
刘金龙%杨军%郭少帅%王永刚%王丛笑%刘海梅%徐群杰%夏永姚
劉金龍%楊軍%郭少帥%王永剛%王叢笑%劉海梅%徐群傑%夏永姚
류금룡%양군%곽소수%왕영강%왕총소%류해매%서군걸%하영요
电池%富锂正极材料%层状%球形%局域结构
電池%富鋰正極材料%層狀%毬形%跼域結構
전지%부리정겁재료%층상%구형%국역결구
batteries%lithium-rich cathode materials%layered%spherical%local structure
富锂正极材料已经成为高能量密度锂离子电池最具有前景的正极材料之一。然而,富锂正极材料电化学性能对其本体和表面的局域结构很敏感,而这些结构跟材料的合成过程密切相关。在目前的工作中,从合成的角度提出了新的思路,Li含量x将影响着富锂Li1.2x Mn0.54 Ni0.13 Co0.13 O2材料的结构特性和电化学性能。基于电化学,XRD,Raman, XPS技术的分析结果,改变Li含量将在材料的本体和表面产生尖晶石相和Li2 CO3物种,会造成所合成的材料局部组分发生变化,进而影响其电压容量曲线。实验结果表明,在正极材料合成的过程中,相比于其他含量,Li含量过量5%(摩尔分数)所合成的样品表现出更好的电化学性能,放电容量高达270 mAh/g。
富鋰正極材料已經成為高能量密度鋰離子電池最具有前景的正極材料之一。然而,富鋰正極材料電化學性能對其本體和錶麵的跼域結構很敏感,而這些結構跟材料的閤成過程密切相關。在目前的工作中,從閤成的角度提齣瞭新的思路,Li含量x將影響著富鋰Li1.2x Mn0.54 Ni0.13 Co0.13 O2材料的結構特性和電化學性能。基于電化學,XRD,Raman, XPS技術的分析結果,改變Li含量將在材料的本體和錶麵產生尖晶石相和Li2 CO3物種,會造成所閤成的材料跼部組分髮生變化,進而影響其電壓容量麯線。實驗結果錶明,在正極材料閤成的過程中,相比于其他含量,Li含量過量5%(摩爾分數)所閤成的樣品錶現齣更好的電化學性能,放電容量高達270 mAh/g。
부리정겁재료이경성위고능량밀도리리자전지최구유전경적정겁재료지일。연이,부리정겁재료전화학성능대기본체화표면적국역결구흔민감,이저사결구근재료적합성과정밀절상관。재목전적공작중,종합성적각도제출료신적사로,Li함량x장영향착부리Li1.2x Mn0.54 Ni0.13 Co0.13 O2재료적결구특성화전화학성능。기우전화학,XRD,Raman, XPS기술적분석결과,개변Li함량장재재료적본체화표면산생첨정석상화Li2 CO3물충,회조성소합성적재료국부조분발생변화,진이영향기전압용량곡선。실험결과표명,재정겁재료합성적과정중,상비우기타함량,Li함량과량5%(마이분수)소합성적양품표현출경호적전화학성능,방전용량고체270 mAh/g。
ABSTRACT:Lithium-rich cathode materials have become one of the most promising cathode materials for high-energy-density lith-ium-ion batteries. However, the electrochemical properties of lithium-rich cathode materials are highly sensitive to the local struc-ture in the bulk and at the surface, which is closely associated with the synthesis process. In the present work, we provided new in-sights into the structural properties and corresponding electrochemical performance of Li1. 2x Mn0. 54 Ni0. 13 Co0. 13 O2 materials as a func-tion of x ( Li content) from a synthesis point of view. The spinel and Li2 CO3 species in the bulk and at the surface arising from the varying amounts of lithium ions would result in the local compositional change within the as-prepared particles and provoke a change in the voltage-capacity profile as determined by electrochemical analysis, XRD, Raman, and XPS observations. Our results re-vealed that the as-prepared sample with 5% excess of Li in molar ratio utilized for the material synthesis showed better electrochem-ical performance in terms of discharge capacity ( ~270 mAh/g) and voltage in comparison to other as-prepared samples with differ-ent Li contents.