CAJ | 학술논문

采用溶剂挥发法，选择2-(4-羧基苯基)苯并咪唑为有机配体成功地合成了一种三维层状结构的铜(Ⅱ)配位聚合物，通过X射线单晶衍射仪对结构进行了表征，结果表明，该配合物属于单斜晶系，空间群P21/c，晶胞参数a=0.9939(2)nm,b/=1.0633(2)nm,c=1.5193(3)nm,α=90.00°,β=92.719(4)°,γ=90.00°,Z=2.中心铜原子通过2-(4-羧基苯基)-苯并咪唑配体的两个氧原子和两个氮原子形成平行四边形的配位环境．
채용용제휘발법，선택2-(4-최기분기)분병미서위유궤배체성공지합성료일충삼유층상결구적동(Ⅱ)배위취합물，통과X사선단정연사의대결구진행료표정，결과표명，해배합물속우단사정계，공간군P21/c，정포삼수a=0.9939(2)nm,b/=1.0633(2)nm,c=1.5193(3)nm,α=90.00°,β=92.719(4)°,γ=90.00°,Z=2.중심동원자통과2-(4-최기분기)-분병미서배체적량개양원자화량개담원자형성평행사변형적배위배경．
A copper(Ⅱ) coordination polymer was successfully synthesized with 4-(1H-benzo[d]imidazol-2-yl) benzoic acid ligand by the solvent evaporation techniques. The crystal structure was determined by X-ray single crystal diffraction.The crystal belongs to monoclinic system and P21/c space group with a= 0.9939(2) nm, b= 1.0633(2) nm, c= 1.5193(3) nm, (3), alpha=90.00°, beta=92.719(4)°, gamma=90.00°, V=1.6038(6)nm3 Z = 2. The copper(Ⅱ) is coordinated with two oxygen atoms and two nitrogen atoms, generating a parallelogram coordination geometry.