皮革与化工
皮革與化工
피혁여화공
LEATHER AND CHEMICALS
2015年
2期
9-12
,共4页
俞凌云%吴孟茹%帅培强%胡江涛%庞晓红%温演庆%董伟
俞凌雲%吳孟茹%帥培彊%鬍江濤%龐曉紅%溫縯慶%董偉
유릉운%오맹여%수배강%호강도%방효홍%온연경%동위
REACH高关注%气相色谱-质谱法%轻工产品%挥发性有机溶剂
REACH高關註%氣相色譜-質譜法%輕工產品%揮髮性有機溶劑
REACH고관주%기상색보-질보법%경공산품%휘발성유궤용제
REACH high attention%Gas chromatography-mass spectrometry%light industrial products%volatile organic solvents
乙二醇单甲醚、乙二醇单乙醚、N,N-二甲基甲酰胺、乙二醇二乙醚、乙二醇乙醚乙酸酯、二乙二醇二甲醚和N-甲基吡咯烷酮是一类优良的有机溶剂,但由于其潜在的生殖毒性,被REACH定为高关注物质。利用气相色谱-质谱法建立检测轻工产品(纺织品、皮革、竹木制品)中这7种挥发性有机溶剂的简单方法。提取方法为30℃甲醇超声水浴提取。方法的回收率高于91.7%。这个方法被成功应用于测定轻工产品中的这7种挥发性有机溶剂。
乙二醇單甲醚、乙二醇單乙醚、N,N-二甲基甲酰胺、乙二醇二乙醚、乙二醇乙醚乙痠酯、二乙二醇二甲醚和N-甲基吡咯烷酮是一類優良的有機溶劑,但由于其潛在的生殖毒性,被REACH定為高關註物質。利用氣相色譜-質譜法建立檢測輕工產品(紡織品、皮革、竹木製品)中這7種揮髮性有機溶劑的簡單方法。提取方法為30℃甲醇超聲水浴提取。方法的迴收率高于91.7%。這箇方法被成功應用于測定輕工產品中的這7種揮髮性有機溶劑。
을이순단갑미、을이순단을미、N,N-이갑기갑선알、을이순이을미、을이순을미을산지、이을이순이갑미화N-갑기필각완동시일류우량적유궤용제,단유우기잠재적생식독성,피REACH정위고관주물질。이용기상색보-질보법건립검측경공산품(방직품、피혁、죽목제품)중저7충휘발성유궤용제적간단방법。제취방법위30℃갑순초성수욕제취。방법적회수솔고우91.7%。저개방법피성공응용우측정경공산품중적저7충휘발성유궤용제。
Excellent organic solvents (ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, N, N-dimethyl formamide and ethylene glycol diethyl ether, glycol ether acetate, diethylene glycol dimethyl ether and N-methyl pyrrolidone) were widely attented by REACH, due to their potential reproductive toxicity. A simple method was followed by Gas chromatography-mass spectrometry (GC-MS) which had been developed for the determination of them in light industrial products (textiles, leathers, bamboo and wood products). Methanol was used as extraction solvent for the ultrasonic extraction at 30℃. The recoveries were higher than 91.7%. The proposed method was successfully applied to the determination of the target compounds in light industrial products with a higher sensitivity.