天津理工大学学报
天津理工大學學報
천진리공대학학보
JOURNAL OF TIANJIN UNIVERSITY OF TECHNOLOGY
2015年
2期
6-9
,共4页
反式CHDM%DSC%结晶动力学
反式CHDM%DSC%結晶動力學
반식CHDM%DSC%결정동역학
trans-CHDM%DSC%non-isothermal crystallization kinetics
采用差示扫描量热法(DSC)考察了反式1,4-环己烷二甲醇(简称反式CHDM)的结晶过程,用不同的模型方程进行了非等温结晶动力学模拟探索。研究结果表明:Jeziony模型和Ozawa方程均能很好地描述反式CHDM的结晶过程,根据模型分析取得较好的线性关系和动力学参数。同时用Kissinger方法计算了反式CHDM的非等温结晶活化能,为辽阳石化的CHDM结晶工业化生产提供数据和理论支持。
採用差示掃描量熱法(DSC)攷察瞭反式1,4-環己烷二甲醇(簡稱反式CHDM)的結晶過程,用不同的模型方程進行瞭非等溫結晶動力學模擬探索。研究結果錶明:Jeziony模型和Ozawa方程均能很好地描述反式CHDM的結晶過程,根據模型分析取得較好的線性關繫和動力學參數。同時用Kissinger方法計算瞭反式CHDM的非等溫結晶活化能,為遼暘石化的CHDM結晶工業化生產提供數據和理論支持。
채용차시소묘량열법(DSC)고찰료반식1,4-배기완이갑순(간칭반식CHDM)적결정과정,용불동적모형방정진행료비등온결정동역학모의탐색。연구결과표명:Jeziony모형화Ozawa방정균능흔호지묘술반식CHDM적결정과정,근거모형분석취득교호적선성관계화동역학삼수。동시용Kissinger방법계산료반식CHDM적비등온결정활화능,위료양석화적CHDM결정공업화생산제공수거화이론지지。
The non-isothermal crystallization of trans-1,4-cyclohexanedimethanol (trans-CHDM) was investigated by differ-ential scanning calorimetry (DSC). Various macro-kinetic models were applied to fit the experimental data of crystallization kinetics under non-isothermal conditions. The results revealed that the Jeziorny approach and Ozawa methods could adequately describe the non-isothermal crystallization process of trans-CHDM, so they could be used to explore some meaningful inter-pretation of the kinetic parameters for trans-CHDM crystallization. Moreover, the activation energy (ΔE) of non-isothermal crystallization for trans-CHDM was also determined according to the Kissinger method.