当代化工
噹代化工
당대화공
CONTEMPORARY CHEMICAL INDUSTRY
2015年
4期
687-690
,共4页
超临界萃取%减压渣油%化学组成
超臨界萃取%減壓渣油%化學組成
초림계췌취%감압사유%화학조성
Supercritical extraction fractionation%Vacuum residue%Chemical composition
对伊朗和沙轻两种减压渣油进行了超临界萃取分离,并对各自窄馏分的性质和结构进行了分析和表征。结果表明两种减渣中硫含量随着馏分变重均匀增加,而金属与残炭主要富集在萃余残渣中;为达到相同的萃取收率,伊朗减渣相比沙轻减渣需要更高的萃取压力,且伊朗减渣中硫与金属在重馏分富集程度更高,二次加工难度大。沙轻减渣杂质含量较低,芳碳率高,烷烃侧链少,相对容易二次加工。
對伊朗和沙輕兩種減壓渣油進行瞭超臨界萃取分離,併對各自窄餾分的性質和結構進行瞭分析和錶徵。結果錶明兩種減渣中硫含量隨著餾分變重均勻增加,而金屬與殘炭主要富集在萃餘殘渣中;為達到相同的萃取收率,伊朗減渣相比沙輕減渣需要更高的萃取壓力,且伊朗減渣中硫與金屬在重餾分富集程度更高,二次加工難度大。沙輕減渣雜質含量較低,芳碳率高,烷烴側鏈少,相對容易二次加工。
대이랑화사경량충감압사유진행료초림계췌취분리,병대각자착류분적성질화결구진행료분석화표정。결과표명량충감사중류함량수착류분변중균균증가,이금속여잔탄주요부집재췌여잔사중;위체도상동적췌취수솔,이랑감사상비사경감사수요경고적췌취압력,차이랑감사중류여금속재중류분부집정도경고,이차가공난도대。사경감사잡질함량교저,방탄솔고,완경측련소,상대용역이차가공。
Two typical residues were separated by supercritical fluid extraction (SFE), properties and structures of the narrow fractions separated by SFE were analyzed and characterized. The results indicate that the sulfur content increases regularly as the fractions become heavier, while there are much more metals in the tail oil than that in other fractions. Compared to Saudi Arabia light residue, higher extraction pressure is needed for Iran residue in order to reach the same extraction yield. Furthermore, there are less impurities and higher aromatic carbon content in the Saudi Arabia light residue than that in the Iran residue, meanwhile, due to more sulfur and metal content accumulating in the Iran residue, its secondary processing is more difficult than Saudi Arabia light residue.