华东交通大学学报
華東交通大學學報
화동교통대학학보
JOURNAL OF EAST CHINA JIAOTONG UNIVERSITY
2015年
2期
136-142
,共7页
鄱阳湖%湿地土壤%氨氮%Freundlich方程%吸附动力学
鄱暘湖%濕地土壤%氨氮%Freundlich方程%吸附動力學
파양호%습지토양%안담%Freundlich방정%흡부동역학
Poyang lake%wetland soils%ammonia nitrogen%Freundlich equation%adsorption kinetics
主要研究鄱阳湖湿地土壤对氨氮的吸附性能。该湿地土壤对氨氮的吸附用Freundlich方程拟合效果较好,且该5个剖面层的n值均接近于1,故该土样对NH4+-N吸附基本符合线性分配过程;在吸附动力学过程中,24 h为此土壤对NH4+-N的吸附平衡时间,伪二级动力学方程能更有效地模拟土样对NH4+-N的动力学吸附,5个剖面层的平衡吸附量qe的大小关系为0~10>10~20>20~30>30~40>40~50 cm,且土样对NH4+-N的平衡吸附量与其中所含有机质呈正相关关系;还考察了pH、温度、固液比对氨氮吸附的影响,结果是pH增大、温度下降、固液比的增大均会促进吸附反应的进行。
主要研究鄱暘湖濕地土壤對氨氮的吸附性能。該濕地土壤對氨氮的吸附用Freundlich方程擬閤效果較好,且該5箇剖麵層的n值均接近于1,故該土樣對NH4+-N吸附基本符閤線性分配過程;在吸附動力學過程中,24 h為此土壤對NH4+-N的吸附平衡時間,偽二級動力學方程能更有效地模擬土樣對NH4+-N的動力學吸附,5箇剖麵層的平衡吸附量qe的大小關繫為0~10>10~20>20~30>30~40>40~50 cm,且土樣對NH4+-N的平衡吸附量與其中所含有機質呈正相關關繫;還攷察瞭pH、溫度、固液比對氨氮吸附的影響,結果是pH增大、溫度下降、固液比的增大均會促進吸附反應的進行。
주요연구파양호습지토양대안담적흡부성능。해습지토양대안담적흡부용Freundlich방정의합효과교호,차해5개부면층적n치균접근우1,고해토양대NH4+-N흡부기본부합선성분배과정;재흡부동역학과정중,24 h위차토양대NH4+-N적흡부평형시간,위이급동역학방정능경유효지모의토양대NH4+-N적동역학흡부,5개부면층적평형흡부량qe적대소관계위0~10>10~20>20~30>30~40>40~50 cm,차토양대NH4+-N적평형흡부량여기중소함유궤질정정상관관계;환고찰료pH、온도、고액비대안담흡부적영향,결과시pH증대、온도하강、고액비적증대균회촉진흡부반응적진행。
This paper mainly studies the Poyang lake wetland soil adsorption of ammonia nitrogen. It maintains that the wetland soil adsorption of ammonia nitrogen with the Freundlich equation fitting effect is good, and the five section layers'n values are close to 1, so the soil samples of ammonia nitrogen adsorption conforms to the basic linear distribution process;In the process of adsorption kinetics, the soil adsorption equilibrium time of ammonia nitrogen is 24 h, and the pseudo secondary dynamics equation can effectively simulate the dynamics of soil sam?ples of ammonia nitrogen adsorption with the equilibrium adsorption quantities from the five section layers being 0~10>10~20>20~30>30~40>40~50 cm, and the equilibrium adsorption of ammonia nitrogen is positively contain?ing organic matters. The paper also examines effects of the pH, temperature and solid-liquid ratio on the absorp?tion of ammonia nitrogen. It finds out that increasing the pH, reducing the temperature and raising the solid-liquid ratio can promote the adsorption reaction.