工程塑料应用
工程塑料應用
공정소료응용
ENGINEERING PLASTICS APPLICATION
2015年
4期
114-118
,共5页
马来酸酐接枝乙烯-辛烯共聚物%尼龙66%增韧%增容
馬來痠酐接枝乙烯-辛烯共聚物%尼龍66%增韌%增容
마래산항접지을희-신희공취물%니룡66%증인%증용
POE-g-MAH%polyamide 66%toughening%compatibilization
采用熔融共混法制备了尼龙(PA)66/马来酸酐接枝乙烯-辛烯共聚物(POE-g-MAH)/纳米TiO2复合材料,通过万能材料试验机、冲击试验机、熔体流动速率(MFR)测试仪等研究了POE-g-MAH对复合材料力学性能及MFR的影响,利用Molau实验和FSEM考察了POE-g-MAH与PA66的相容性。结果显示,POE-g-MAH与PA66基体有很好的相容性;随着POE-g-MAH用量的增加,PA66/POE-g-MAH/纳米TiO2复合材料的缺口冲击强度逐渐增加,拉伸强度、弯曲强度、拉伸弹性模量及MFR逐渐降低;当POE-g-MAH质量分数为12%时,复合材料的综合性能最佳,缺口冲击强度、拉伸强度、弯曲强度、拉伸弹性模量和MFR分别为20.89 kJ/m2,41.15 MPa,64.2 MPa,1428.15 MPa和19.2 g/(10 min)。
採用鎔融共混法製備瞭尼龍(PA)66/馬來痠酐接枝乙烯-辛烯共聚物(POE-g-MAH)/納米TiO2複閤材料,通過萬能材料試驗機、遲擊試驗機、鎔體流動速率(MFR)測試儀等研究瞭POE-g-MAH對複閤材料力學性能及MFR的影響,利用Molau實驗和FSEM攷察瞭POE-g-MAH與PA66的相容性。結果顯示,POE-g-MAH與PA66基體有很好的相容性;隨著POE-g-MAH用量的增加,PA66/POE-g-MAH/納米TiO2複閤材料的缺口遲擊彊度逐漸增加,拉伸彊度、彎麯彊度、拉伸彈性模量及MFR逐漸降低;噹POE-g-MAH質量分數為12%時,複閤材料的綜閤性能最佳,缺口遲擊彊度、拉伸彊度、彎麯彊度、拉伸彈性模量和MFR分彆為20.89 kJ/m2,41.15 MPa,64.2 MPa,1428.15 MPa和19.2 g/(10 min)。
채용용융공혼법제비료니룡(PA)66/마래산항접지을희-신희공취물(POE-g-MAH)/납미TiO2복합재료,통과만능재료시험궤、충격시험궤、용체류동속솔(MFR)측시의등연구료POE-g-MAH대복합재료역학성능급MFR적영향,이용Molau실험화FSEM고찰료POE-g-MAH여PA66적상용성。결과현시,POE-g-MAH여PA66기체유흔호적상용성;수착POE-g-MAH용량적증가,PA66/POE-g-MAH/납미TiO2복합재료적결구충격강도축점증가,랍신강도、만곡강도、랍신탄성모량급MFR축점강저;당POE-g-MAH질량분수위12%시,복합재료적종합성능최가,결구충격강도、랍신강도、만곡강도、랍신탄성모량화MFR분별위20.89 kJ/m2,41.15 MPa,64.2 MPa,1428.15 MPa화19.2 g/(10 min)。
The polyamide(PA)66/maleic anhydride grafted ethylene octene copolymer(POE-g-MAH)/nano-TiO2 composites were prepared by melt blending method. The effects of POE-g-MAH on the mechanical properties and melt flow rate(MFR) of PA66/nano-TiO2 composites were studied using universal material testing machine,impact testing machine,melt flow rate tester,etc.. Molau experiments and FSEM were used to examine the compatibility of POE-g-MAH and PA66. The results show that,POE-g-MAH is well compatible with PA66. With the increase of POE-g-MAH content,the notch impact strength of the composites increases,the tensile strength,bending strength,the tensile elastic modulus and MFR decrease gradually. When POE-g-MAH content is 12%,the comprehensive properties of the composites achieve the best,the notched impact strength,tensile strength, bending strength,tensile elastic modulus and MFR are 20.89 kJ/m2,41.15 MPa,64.2 MPa ,1428.15 MPa and 19.2 g/(10 min), respectively.