环境科学
環境科學
배경과학
CHINESE JOURNAL OF ENVIRONMENTAL SCIENCE
2015年
3期
989-994
,共6页
宋敏%张琳萍%钟毅%徐红%毛志平
宋敏%張琳萍%鐘毅%徐紅%毛誌平
송민%장림평%종의%서홍%모지평
双核锰配合物%非均相%CWPO%活性蓝P-3R%脱色
雙覈錳配閤物%非均相%CWPO%活性藍P-3R%脫色
쌍핵맹배합물%비균상%CWPO%활성람P-3R%탈색
binuclear manganese complex%heterogeneous%CWPO%reactive blue P-3R%decolorization
以微胶囊技术为负载手段,将一种具有高效催化氧化活性的双核锰配合物MnL负载到了乙基纤维素微球中,采用电感耦合等离子发射光谱仪( ICP)、紫外可见( UV-VIS)光谱扫描、扫描电镜( SEM)、透射电镜( TEM)等表征测试手段对该微球负载催化剂进行了相关的形态结构表征,发现催化剂MnL在乙基纤维素微球基质内分散良好,并保持了其原结构的完整性。将制备的该MnL负载微球用于催化活性蓝P-3R溶液模拟染料废水的氧化脱色反应,表现出了很好的催化氧化性能。催化氧化脱色实验发现,其不仅可以催化活性蓝P-3R溶液至完全氧化脱色,并具备一定的可循环利用性,在经过4次循环使用后仍可催化活性蓝P-3R溶液达到70%以上的氧化脱色率,可以作为一种新型的非均相CWPO催化剂用于染料废水的脱色处理。
以微膠囊技術為負載手段,將一種具有高效催化氧化活性的雙覈錳配閤物MnL負載到瞭乙基纖維素微毬中,採用電感耦閤等離子髮射光譜儀( ICP)、紫外可見( UV-VIS)光譜掃描、掃描電鏡( SEM)、透射電鏡( TEM)等錶徵測試手段對該微毬負載催化劑進行瞭相關的形態結構錶徵,髮現催化劑MnL在乙基纖維素微毬基質內分散良好,併保持瞭其原結構的完整性。將製備的該MnL負載微毬用于催化活性藍P-3R溶液模擬染料廢水的氧化脫色反應,錶現齣瞭很好的催化氧化性能。催化氧化脫色實驗髮現,其不僅可以催化活性藍P-3R溶液至完全氧化脫色,併具備一定的可循環利用性,在經過4次循環使用後仍可催化活性藍P-3R溶液達到70%以上的氧化脫色率,可以作為一種新型的非均相CWPO催化劑用于染料廢水的脫色處理。
이미효낭기술위부재수단,장일충구유고효최화양화활성적쌍핵맹배합물MnL부재도료을기섬유소미구중,채용전감우합등리자발사광보의( ICP)、자외가견( UV-VIS)광보소묘、소묘전경( SEM)、투사전경( TEM)등표정측시수단대해미구부재최화제진행료상관적형태결구표정,발현최화제MnL재을기섬유소미구기질내분산량호,병보지료기원결구적완정성。장제비적해MnL부재미구용우최화활성람P-3R용액모의염료폐수적양화탈색반응,표현출료흔호적최화양화성능。최화양화탈색실험발현,기불부가이최화활성람P-3R용액지완전양화탈색,병구비일정적가순배이용성,재경과4차순배사용후잉가최화활성람P-3R용액체도70%이상적양화탈색솔,가이작위일충신형적비균상CWPO최화제용우염료폐수적탈색처리。
Binuclear manganese complex ( MnL) , with high catalytic activity, was encapsulated into ethyl cellulose microspheres via a microencapsulation technique. The characterization of the catalyst through ICP, UV-VIS, SEM and TEM revealed that MnL was well distributed within the ethyl cellulose matrix. The results of UV-VIS confirmed the structural integrity of MnL after the encapsulation process. The MnL loaded microspheres exhibited an excellent catalytic property in the oxidative decolorization of Reactive Blue P-3R, which was used to simulate the dyestuff wastewater. The dye solution was completely decolorized under the catalyzing action of these microspheres. What’s more, these MnL loaded microspheres could be reused for at least 4 times and the decolorization degree of Reactive Blue P-3R was maintained above 70%. The results demonstrated the potential application of the microsphere-supported MnL as a novel heterogeneous CWPO catalyst for the decolorization of wastewater containing dyestuff.