东北林业大学学报
東北林業大學學報
동북임업대학학보
JOURNAL OF NORTHEAST FORESTRY UNIVERSITY
2015年
4期
73-76
,共4页
溶剂抽提物%尾巨桉%热变色%过热蒸汽处理
溶劑抽提物%尾巨桉%熱變色%過熱蒸汽處理
용제추제물%미거안%열변색%과열증기처리
Solvent extraction%Eucalyptus urophylla ×Ecu alyptus rg andis%Color change%Overheating steam treat-ment
为探讨溶剂抽提物对尾巨桉热变色的影响,在过热蒸气条件下对抽提物进行热处理,之后采用冷水、热水、乙醇、甲醇、丙酮、正己烷等6种溶剂对热处理前后的尾巨桉木粉进行抽提,对热处理前后经过抽提的木粉进行色度指数的测定和红外光谱分析,并对抽提物进行紫外光谱分析。结果表明:①极性溶剂抽提物对尾巨桉颜色及其热处理后颜色变化影响较大,其中热水抽提物对颜色的影响最显著;②抽提物热处理后共轭结构增加,共轭体系能量降低,吸收带延伸至可见光范围,是木材受热后颜色加深的重要原因;③热处理后,尾巨桉木粉ΔL倡为负值,即颜色变深,木材颜色均匀美观,可提高利用价值。
為探討溶劑抽提物對尾巨桉熱變色的影響,在過熱蒸氣條件下對抽提物進行熱處理,之後採用冷水、熱水、乙醇、甲醇、丙酮、正己烷等6種溶劑對熱處理前後的尾巨桉木粉進行抽提,對熱處理前後經過抽提的木粉進行色度指數的測定和紅外光譜分析,併對抽提物進行紫外光譜分析。結果錶明:①極性溶劑抽提物對尾巨桉顏色及其熱處理後顏色變化影響較大,其中熱水抽提物對顏色的影響最顯著;②抽提物熱處理後共軛結構增加,共軛體繫能量降低,吸收帶延伸至可見光範圍,是木材受熱後顏色加深的重要原因;③熱處理後,尾巨桉木粉ΔL倡為負值,即顏色變深,木材顏色均勻美觀,可提高利用價值。
위탐토용제추제물대미거안열변색적영향,재과열증기조건하대추제물진행열처리,지후채용랭수、열수、을순、갑순、병동、정기완등6충용제대열처리전후적미거안목분진행추제,대열처리전후경과추제적목분진행색도지수적측정화홍외광보분석,병대추제물진행자외광보분석。결과표명:①겁성용제추제물대미거안안색급기열처리후안색변화영향교대,기중열수추제물대안색적영향최현저;②추제물열처리후공액결구증가,공액체계능량강저,흡수대연신지가견광범위,시목재수열후안색가심적중요원인;③열처리후,미거안목분ΔL창위부치,즉안색변심,목재안색균균미관,가제고이용개치。
Overheating steam treatment can darken the color of Eucalyptus urophylla×Eucalyptus grandis wood and make it look like precious wood, which can improve its utility value.For studying the effect of overheating steam treatment on discolora-tion of Eucalyptus urophylla ×Eucalyptus grandis wood, we extracted the wood powder before and after heating treatment with cold water, hot water, alcohol, methyl alcohol, and acetone and n-hexane, and measured the color parameters of the samples before and after extracted.We used ultraviolet absorption spectrum and the FTIR spectra to evaluate chemical changes of extractives and wood powder.Polar solvents extract was more effective on color and color changes of E.grandis wood powder after heat treatment.Hot water extraction had the most important influence on wood color.The important rea-sons of color deepen after heat treatment were:after heat treatment, the conjugated structures of extractives increased, and the energy of conjugated system decreased, and the absorption band extended to the visible light range.After heat treat-ment,ΔL* value of E.urpoh ylla×E.grandis wood powder was negative, which meant the color was deepen, and the color of wood was uniform and beautiful with high utility value.