高校化学工程学报
高校化學工程學報
고교화학공정학보
JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES
2015年
2期
451-456
,共6页
闫云飞%张智恩%晏水平%鞠顺祥%张力%张继广
閆雲飛%張智恩%晏水平%鞠順祥%張力%張繼廣
염운비%장지은%안수평%국순상%장력%장계엄
中空纤维膜%CO 2%烟气%脱除率%数值模拟
中空纖維膜%CO 2%煙氣%脫除率%數值模擬
중공섬유막%CO 2%연기%탈제솔%수치모의
hollow fiber membrane%CO2%flue gas%removal efficiency%numerical simulation
相对于传统的脱碳方法,中空纤维膜脱除烟气中CO 2是一种清洁、高效的技术方法。运用有限单元法建立了一个疏水性中空纤维膜脱除烟气中CO 2的二维模型,考察了膜丝直径、壁厚、孔隙率、曲折因子、纤维膜根数、膜柱内径和长度等方面对CO 2脱除率的影响,模型结果与实验值相符。结果表明四种吸收剂的脱除率从大到小依次为EDA>MEA>DEA>AMP。当液速为0.1 m·s–1、气速0.211 m·s–1、操作压力为0.1 MPa时,减小曲折因子、膜丝壁厚和膜柱内径,增大孔隙率、膜丝内径与膜柱长度都有利于膜吸收CO 2。
相對于傳統的脫碳方法,中空纖維膜脫除煙氣中CO 2是一種清潔、高效的技術方法。運用有限單元法建立瞭一箇疏水性中空纖維膜脫除煙氣中CO 2的二維模型,攷察瞭膜絲直徑、壁厚、孔隙率、麯摺因子、纖維膜根數、膜柱內徑和長度等方麵對CO 2脫除率的影響,模型結果與實驗值相符。結果錶明四種吸收劑的脫除率從大到小依次為EDA>MEA>DEA>AMP。噹液速為0.1 m·s–1、氣速0.211 m·s–1、操作壓力為0.1 MPa時,減小麯摺因子、膜絲壁厚和膜柱內徑,增大孔隙率、膜絲內徑與膜柱長度都有利于膜吸收CO 2。
상대우전통적탈탄방법,중공섬유막탈제연기중CO 2시일충청길、고효적기술방법。운용유한단원법건립료일개소수성중공섬유막탈제연기중CO 2적이유모형,고찰료막사직경、벽후、공극솔、곡절인자、섬유막근수、막주내경화장도등방면대CO 2탈제솔적영향,모형결과여실험치상부。결과표명사충흡수제적탈제솔종대도소의차위EDA>MEA>DEA>AMP。당액속위0.1 m·s–1、기속0.211 m·s–1、조작압력위0.1 MPa시,감소곡절인자、막사벽후화막주내경,증대공극솔、막사내경여막주장도도유리우막흡수CO 2。
Compared with traditional CO2 separation methods, the absorption of CO2 in flue gas with hollow fiber membrane is a clean and efficient decarbonization technology. This paper used the finite element method and established a 2D model of hydrophobic hollow fiber membrane for the removal of CO2 in flue gas. The CO2-removal efficiency was investigated from the membrane diameter, thickness, porosity, tortuosity, the number of fibers, membrane column diameter and length. The modeling results are consistent with the experimental values. The results show that the sequence of absorption efficiency of four absorbents is EDA>MEA>DEA>AMP. Decreasing the tortuosity, thickness, and column diameter, or increasing the porosity, fiber diameter, and membrane length, is beneficial to the membrane absorption of CO2under the conditions of 0.1 m·s–1liquid velocity, 0.211 m·s–1gas velocity and 0.1 MPa operation pressure.