化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2015年
5期
1277-1282
,共6页
唐晓东%胡涛%李晶晶%张永汾%陈露
唐曉東%鬍濤%李晶晶%張永汾%陳露
당효동%호도%리정정%장영분%진로
车用燃料%电化学%氧化%还原%脱硫
車用燃料%電化學%氧化%還原%脫硫
차용연료%전화학%양화%환원%탈류
vehicle fuel%electrochemistry%oxidation%reduction%desulfurization
随着空气污染的日益严重及环保法规的逐步完善,车用燃料清洁化生产已势在必行。作为一种新型脱硫技术,电化学脱硫近年来研究较多。车用燃料电化学脱硫技术包括氧化脱硫及还原脱硫。相对于传统加氢脱硫,电化学脱硫具有反应条件温和、选择性高、工艺流程简单及易于自动控制等特点。本文综述了国内外车用燃料电化学脱硫的研究现状,从反应机理、实验方法、脱硫效果等方面详细介绍了电化学脱硫的研究进展。提出了深入研究反应机理、寻找新型电极材料、配制复合电解液以及开发电化学组合脱硫工艺是未来车用燃料电化学脱硫的发展方向。
隨著空氣汙染的日益嚴重及環保法規的逐步完善,車用燃料清潔化生產已勢在必行。作為一種新型脫硫技術,電化學脫硫近年來研究較多。車用燃料電化學脫硫技術包括氧化脫硫及還原脫硫。相對于傳統加氫脫硫,電化學脫硫具有反應條件溫和、選擇性高、工藝流程簡單及易于自動控製等特點。本文綜述瞭國內外車用燃料電化學脫硫的研究現狀,從反應機理、實驗方法、脫硫效果等方麵詳細介紹瞭電化學脫硫的研究進展。提齣瞭深入研究反應機理、尋找新型電極材料、配製複閤電解液以及開髮電化學組閤脫硫工藝是未來車用燃料電化學脫硫的髮展方嚮。
수착공기오염적일익엄중급배보법규적축보완선,차용연료청길화생산이세재필행。작위일충신형탈류기술,전화학탈류근년래연구교다。차용연료전화학탈류기술포괄양화탈류급환원탈류。상대우전통가경탈류,전화학탈류구유반응조건온화、선택성고、공예류정간단급역우자동공제등특점。본문종술료국내외차용연료전화학탈류적연구현상,종반응궤리、실험방법、탈류효과등방면상세개소료전화학탈류적연구진전。제출료심입연구반응궤리、심조신형전겁재료、배제복합전해액이급개발전화학조합탈류공예시미래차용연료전화학탈류적발전방향。
With increasingly serious air pollution and perfecting environmental protection laws,cleaner production of vehicle fuel is imperative. As a new type of desulfurization technology,more and more researches have focused on electrochemical desulfurization in recent years. Electrochemical desulfurization of vehicle fuel includes oxidation desulfurization and reduction desulfurization. Compared with the traditional hydrogenation desulfurization methods and other non-hydrogenation desulfurization methods,the electrochemistry desulfurization technology as a new desulfurization technology possesses the advantages of moderate operating conditions,high removal effectiveness of sulfur compounds,more simple process and automatic control. Advances in electrochemical oxidation desulfurization and reduction desulfurization,including reaction mechanism,experimental methods and desulfurization effect,are reviewed. Furthermore,the development and application trends of electrochemical desulfurization are proposed. Reaction mechanism,new electrode materials, composite electrolyte,and combination of composite desulfurization process with other desulfurization technology will become the future research directions of electrochemical desulfurization.