化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2015年
5期
1323-1331
,共9页
许定佳%郑永付%张松%赵莹莹%李文卓%沈丁丰
許定佳%鄭永付%張鬆%趙瑩瑩%李文卓%瀋丁豐
허정가%정영부%장송%조형형%리문탁%침정봉
弱凝胶%调剖%成胶机理%评价方法%计算机分子动力学模拟
弱凝膠%調剖%成膠機理%評價方法%計算機分子動力學模擬
약응효%조부%성효궤리%평개방법%계산궤분자동역학모의
weak gel%profile control%gelling mechanism%evaluation method%computer molecular dynamic simulation
弱凝胶体系调驱技术是通过降低油田高渗透层渗透率、提高水驱波及系数、改善水驱开发效果来实现原油稳产的重要手段。本文综述了近年来原油开采过程中用于调驱技术的弱凝胶体系基本组成,不同交联剂对弱凝胶体系的成胶机理和成胶条件及弱凝胶体系性能的评价方法。总结了稳定剂、杀菌剂、抗盐剂、延迟剂等助剂和温度、矿化度、pH值等环境因素对弱凝胶体系性能的影响;概述了弱凝胶体系的矿场应用技术现状和现有弱凝胶体系在调剖应用中仍存在的问题。提出在传统表观方法研究弱凝胶交联机理的基础上,利用激光光散射法、原子力显微镜和计算机分子动力学模拟等技术加强对弱凝胶交联微观机理研究,为开发新型长效且廉价的调剖剂提供理论依据。
弱凝膠體繫調驅技術是通過降低油田高滲透層滲透率、提高水驅波及繫數、改善水驅開髮效果來實現原油穩產的重要手段。本文綜述瞭近年來原油開採過程中用于調驅技術的弱凝膠體繫基本組成,不同交聯劑對弱凝膠體繫的成膠機理和成膠條件及弱凝膠體繫性能的評價方法。總結瞭穩定劑、殺菌劑、抗鹽劑、延遲劑等助劑和溫度、礦化度、pH值等環境因素對弱凝膠體繫性能的影響;概述瞭弱凝膠體繫的礦場應用技術現狀和現有弱凝膠體繫在調剖應用中仍存在的問題。提齣在傳統錶觀方法研究弱凝膠交聯機理的基礎上,利用激光光散射法、原子力顯微鏡和計算機分子動力學模擬等技術加彊對弱凝膠交聯微觀機理研究,為開髮新型長效且廉價的調剖劑提供理論依據。
약응효체계조구기술시통과강저유전고삼투층삼투솔、제고수구파급계수、개선수구개발효과래실현원유은산적중요수단。본문종술료근년래원유개채과정중용우조구기술적약응효체계기본조성,불동교련제대약응효체계적성효궤리화성효조건급약응효체계성능적평개방법。총결료은정제、살균제、항염제、연지제등조제화온도、광화도、pH치등배경인소대약응효체계성능적영향;개술료약응효체계적광장응용기술현상화현유약응효체계재조부응용중잉존재적문제。제출재전통표관방법연구약응효교련궤리적기출상,이용격광광산사법、원자력현미경화계산궤분자동역학모의등기술가강대약응효교련미관궤리연구,위개발신형장효차렴개적조부제제공이론의거。
Oil production can be improved by profile control technologies,including the decrease of the permeability of high permeable zone and the increase of water-flooded sweep efficiency contributions. The most important chemical systems applied in present profile control technologies are weak gel systems with many great merits in promoting oil output. In this paper,we make a summarization on following aspects:The basic component of weak gel systems used in oil exploration by profile control technologies in recent years,the mechanism and condition of the formation of weak gel systems initiated by different crosslinking agents,and the evaluation methods of the performance of weak gel systems. It is also discussed that how additives,including stabilizing agents,bactericides,salt resistances,delay agents,etc.,and environmental factors,such as temperature,salinity,pH,etc., affect the properties of weak gel systems. Based on the current application of weak gel systems,it is pointed out that there are still some problems unsolved in the profile control processes when the weak gel systems are employed. To develop new effective and inexpensive profile control agents and make the corresponding theoretical basis to new agents,methods to investigate the gelling mechanism of weak gel systems need to be improved. The improvement is going to be a transition from traditional macroscopic research methods to microscopic research methods,such as the laser light scattering,atomic force microscope and computer molecular dynamic simulation,etc.