化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2015年
5期
1295-1299
,共5页
郑修新%赵甲%孙国方%高鹏%费亚南%刘有鹏%于海斌
鄭脩新%趙甲%孫國方%高鵬%費亞南%劉有鵬%于海斌
정수신%조갑%손국방%고붕%비아남%류유붕%우해빈
催化剂%加氢%加氢脱硫%萘%十氢萘
催化劑%加氫%加氫脫硫%萘%十氫萘
최화제%가경%가경탈류%내%십경내
catalyst%hydrogenation%hydrodesulfurization%naphthalene%decalin
综述了几类萘加氢催化剂的研究进展,重点介绍了传统的非贵金属 Ni、Mo、Co、W 等加氢催化剂和贵金属加氢催化剂,阐述了上述催化剂在萘加氢过程中的应用,并比较了各自在萘加氢活性、选择性和耐硫性等方面的优缺点,简单介绍了过渡金属碳化物、氮化物、磷化物、硅化物加氢催化剂的研究进展,并与前述两种催化剂进行了比较,通过对现有文献的总结指出了萘加氢催化剂的发展方向,提出新型加氢催化剂的研发仍然是实现萘及其他多环芳烃高效利用的根本出路。
綜述瞭幾類萘加氫催化劑的研究進展,重點介紹瞭傳統的非貴金屬 Ni、Mo、Co、W 等加氫催化劑和貴金屬加氫催化劑,闡述瞭上述催化劑在萘加氫過程中的應用,併比較瞭各自在萘加氫活性、選擇性和耐硫性等方麵的優缺點,簡單介紹瞭過渡金屬碳化物、氮化物、燐化物、硅化物加氫催化劑的研究進展,併與前述兩種催化劑進行瞭比較,通過對現有文獻的總結指齣瞭萘加氫催化劑的髮展方嚮,提齣新型加氫催化劑的研髮仍然是實現萘及其他多環芳烴高效利用的根本齣路。
종술료궤류내가경최화제적연구진전,중점개소료전통적비귀금속 Ni、Mo、Co、W 등가경최화제화귀금속가경최화제,천술료상술최화제재내가경과정중적응용,병비교료각자재내가경활성、선택성화내류성등방면적우결점,간단개소료과도금속탄화물、담화물、린화물、규화물가경최화제적연구진전,병여전술량충최화제진행료비교,통과대현유문헌적총결지출료내가경최화제적발전방향,제출신형가경최화제적연발잉연시실현내급기타다배방경고효이용적근본출로。
Research progress in several types of catalysts for the hydrogenation of naphthalene was reviewed,such as the typical conventional catalysts based on the transition metals of Ni,Mo,Co, W and noble metal catalysts. Their application on the hydrogenation process of naphthalene and their advantages and disadvantages in activity,selectivity and sulfur tolerance were discussed. Progress in transition metal carbides,nitrides,phosphides and silicides catalysts was also introduced briefly and compared with former catalysts. The development trend of catalysts for naphthalene hydrogenation was pointed out. It indicated that the development of new catalysts was still the fundamental solution to the efficient utilization of naphthalene and other polycyclic aromatics.