CAJ | 학술논문

以不同的大分子多糖为骨架材料，通过三步反应以触须式引入季铵基团，从而制得4种具有高通量的强碱性阴离子交换树脂：淀粉基树脂、微晶纤维素基树脂、纤维素微球基树脂及琼脂糖微球基树脂。研究树脂对曙红Y的吸附，探讨了时间、溶液pH值和染料初始浓度对染料去除率的影响。结果表明，4种树脂在pH值为1～12范围内对染料的去除效果稳定；5min内4种树脂基本都达到了吸附平衡，其中琼脂糖微球基树脂按1g/L投放时，在2min内即可将200mg/L的曙红Y完全去除；通过拟合得知，4种树脂的吸附动力学符合拟一级动力学方程，等温线符合Freundlich等温线方程。这4种树脂尤其是琼脂糖微球基树脂在吸附速率及吸附量上均具有较大优势，但4种树脂的原料成本不一，可根据需求选用不同的树脂。
이불동적대분자다당위골가재료，통과삼보반응이촉수식인입계안기단，종이제득4충구유고통량적강감성음리자교환수지：정분기수지、미정섬유소기수지、섬유소미구기수지급경지당미구기수지。연구수지대서홍Y적흡부，탐토료시간、용액pH치화염료초시농도대염료거제솔적영향。결과표명，4충수지재pH치위1～12범위내대염료적거제효과은정；5min내4충수지기본도체도료흡부평형，기중경지당미구기수지안1g/L투방시，재2min내즉가장200mg/L적서홍Y완전거제；통과의합득지，4충수지적흡부동역학부합의일급동역학방정，등온선부합Freundlich등온선방정。저4충수지우기시경지당미구기수지재흡부속솔급흡부량상균구유교대우세，단4충수지적원료성본불일，가근거수구선용불동적수지。
With different macromolecular polysaccharide as framework materials,four high-capacity strong base anion exchange resins were prepared by the introduction of quaternary ammonium groups in tentacle-type by three chemical reactions. The resins were applied to remove Eosin Y,and the effects of adsorption time,pH and dye concentration on the removal were also studied. It indicated that all resins could function well in the pH range of 1 to 12. Four resins reached equilibrium in 5 min,and agarose beads resin can completely remove 200 mg/L Eosin Y in 2 min at 1 g/L feeding rate. Fitting the data into kinetic models and isotherm gave the conclusion that the adsorption behavior matched better with pseudo-first-order kinetic and Freundlich isotherm. The adsorption rate and adsorption capacity of four resins,especially agarose beads resin,have a greater advantage. It can be selected according to the needs,because the costs of raw materials in four resins are different.