CAJ | 학술논문

呋咱类化合物因能量密度高、综合性能好、可作为炸药和推进剂等广泛应用于军事领域。3,4-二氨基呋咱（DAF）作为重要的前体化合物，其大规模合成为呋咱类高能量密度衍生物的应用奠定了基础。本文首先介绍了DAF的合成工艺及其氧化机理，并综述了以其为中间体得到的氧化物、大环、长链和稠环化合物的国内外合成方法及性能，表明呋咱类化合物爆轰性能优良，具有潜在应用前景；但是，不少硝基取代或多呋咱环衍生物存在安定性差、感度高的缺点。据此，提出设计合成新型钝感高能呋咱衍生物是解决上述不足的有效方法；DAF的合成工艺研究及增大呋咱类化合物开发力度是未来的发展重点。
부찰류화합물인능량밀도고、종합성능호、가작위작약화추진제등엄범응용우군사영역。3,4-이안기부찰（DAF）작위중요적전체화합물，기대규모합성위부찰류고능량밀도연생물적응용전정료기출。본문수선개소료DAF적합성공예급기양화궤리，병종술료이기위중간체득도적양화물、대배、장련화주배화합물적국내외합성방법급성능，표명부찰류화합물폭굉성능우량，구유잠재응용전경；단시，불소초기취대혹다부찰배연생물존재안정성차、감도고적결점。거차，제출설계합성신형둔감고능부찰연생물시해결상술불족적유효방법；DAF적합성공예연구급증대부찰류화합물개발력도시미래적발전중점。
Furazan energetic compounds are widely used as explosives or propellants in the military field because of their high energy density and good comprehensive properties. The large-scale synthesis of 3,4-diaminofurazan (DAF) as an important precursor compound lays a foundation for the application of furazan high energy density derivatives. In this paper,synthesis process and oxidation mechanism of DAF are introduced. Based on DAF as an intermediate,synthesis methods and properties of oxide and large ring,long chain,fused ring compounds are reviewed,which indicates that the detonation properties of furazan compounds are good and have potential application prospects. However,many nitro substituted or more furazan ring derivatives have disadvantages of poor stability and high sensitivity. According to this,the design of synthesizing new insensitive energetic furazan derivatives is considered as the effective strategy. Research on DAF synthesis process and strengthening development of furazan compounds are focuses of the future.